252360

Morpholine

ACS reagent, ≥99.0%

• Sinónimos: Tetrahydro-1,4-oxazine
• Fórmula empírica (notación de Hill): C₄H₉NO
• Número de CAS: 110-91-8
• Peso molecular: 87.12
• Beilstein/REAXYS Number: 102549
• EC Number: 203-815-1
• MDL number: MFCD00005972
• UNSPSC Code: 12352100
• eCl@ss: 39162409
• PubChem Substance ID: 24855203
• NACRES: NA.21

Propiedades

• grade: ACS reagent
• Quality Level: 200
• vapor density: 3 (vs air)
• vapor pressure: 31 mmHg ( 38 °C); 7 mmHg ( 20 °C)
• assay: ≥99.0%
• form: liquid
• autoignition temp.: 590 °F
• expl. lim.: 10.8 %
• color: APHA: ≤15
• refractive index: n20/D 1.454 (lit.)
• bp: 126.0-130.0 °C; 129 °C (lit.)
• mp: −7-−5 °C (lit.)
• density: 0.996 g/mL at 25 °C (lit.)
• SMILES string: C1COCCN1
• InChI: 1S/C4H9NO/c1-3-6-4-2-5-1/h5H,1-4H2
• InChI key: YNAVUWVOSKDBBP-UHFFFAOYSA-N

Descripción

Application

Morpholine may be used in the preparation of derivatives such as 4-benzoyloxymorpholine and 1-morpholinopropan-1-one. It may also be used in the preparation of (S)-3,3′-bis-morpholinomethyl-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-bi-2-naphthol, a bifunctional chiral catalyst for asymmetric synthesis. As a base, morpholine can be used in the preparation of 1,3-disubstituted allenes from terminal alkynes and aldehydes.

Información de seguridad

• pictograms: GHS02,GHS06,GHS08,GHS05
• signalword: Danger
• hcodes: H226,H302,H311 + H331,H314,H361fd
• pcodes: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Repr. 2 - Skin Corr. 1B
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 1
• flash_point_f: 87.8 °F - closed cup
• flash_point_c: 31 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter