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Merck

00942

Supelco

N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide

for GC derivatization, LiChropur, ≥95.0% (GC), with 1% tert-Butyldimethylchlorosilane

Sinónimos:

N-Methyl-N-tert-butyldimethylsilyltrifluoroacetamide, MTBSTFA + 1% TBDMSCl, Silylating mixture VI

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About This Item

Fórmula empírica (notación de Hill):
C9H18F3NOSi
Número de CAS:
Peso molecular:
241.33
Beilstein/REAXYS Number:
3606546
MDL number:
UNSPSC Code:
41116105
PubChem Substance ID:
NACRES:
NA.22

product name

N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide with 1% tert-Butyldimethylchlorosilane, for GC derivatization, LiChropur, ≥95.0% (GC)

grade

for GC derivatization

Quality Level

assay

≥95.0% (GC)

form

liquid

quality

LiChropur

reaction suitability

reagent type: derivatization reagent
reaction type: Silylations

technique(s)

gas chromatography (GC): suitable

impurities

0.5-1.5% tert-butyldimethylchlorosilane

storage temp.

2-8°C

SMILES string

CN(C(=O)C(F)(F)F)[Si](C)(C)C(C)(C)C

InChI

1S/C9H18F3NOSi/c1-8(2,3)15(5,6)13(4)7(14)9(10,11)12/h1-6H3

InChI key

QRKUHYFDBWGLHJ-UHFFFAOYSA-N

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General description

N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamidewith 1% tert-Butyldimethylchlorosilane (TBDMS) is a derivatizing reagentcommonly used in gas chromatography (GC) and gas chromatography-massspectrometry (GC-MS).

Application

MTBSTFA + 1% TBDMSCl can be used as a derivatizing reagentin the analysis of:
  • Organic acid profile in human serum by gaschromatography/mass spectrometry (GC/MS).
  • Nerveagents and their breakdown products by GC–MS-MS method.

Recommended products

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

related product

Referencia del producto
Descripción
Precios

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

113.0 °F - closed cup

flash_point_c

45 °C - closed cup


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Mass spectrometry of anabolic steroids as their tert-butyldimethylsilyl ether derivatives.
Steffenrud, S.
Rapid Communications in Mass Spectrometry, 10, 1698-1702 (1996)
Gas chromatography/mass spectrometry analysis of organic acid profiles in human serum: A protocol of direct ultrasound-assisted derivatization
Zhang MJ, et al.
Rapid Communications in Mass Spectrometry, 35(17), e9149-e9149 (2021)
The Application of a single-column GC--MS-MS method for the rapid analysis of chemical warfare agents and breakdown products
Young SA, et al.},
Journal of Analytical Toxicology, 43(3), 179-187 (2019)
Yalun Arifin et al.
Applied microbiology and biotechnology, 98(21), 9033-9044 (2014-08-16)
Sugarcane is the most efficient large-scale crop capable of supplying sufficient carbon substrate, in the form of sucrose, needed during fermentative feedstock production. However, sucrose metabolism in Escherichia coli is not well understood because the two most common strains, E.
Xue Shi et al.
Journal of proteome research, 14(2), 1174-1182 (2015-01-17)
The interactions among the gut, liver, and immune system play an important role in liver disease. Probiotics have been used for the treatment and prevention of many pathological conditions, including liver diseases. Comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC-TOF

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