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Merck

A88107

Sigma-Aldrich

p-Anisaldehyde

98%

Sinónimos:

p-Methoxybenzaldehyde, 4-Methoxybenzaldehyde, Aubépine

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About This Item

Fórmula lineal:
CH3OC6H4CHO
Número de CAS:
Peso molecular:
136.15
Beilstein:
471382
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
NACRES:
NA.22
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densidad de vapor

4.7 (vs air)

Nivel de calidad

Ensayo

98%

Formulario

liquid

índice de refracción

n20/D 1.573 (lit.)

bp

248 °C (lit.)

mp

−1 °C (lit.)

densidad

1.119 g/mL at 25 °C (lit.)

cadena SMILES

[H]C(=O)c1ccc(OC)cc1

InChI

1S/C8H8O2/c1-10-8-4-2-7(6-9)3-5-8/h2-6H,1H3

Clave InChI

ZRSNZINYAWTAHE-UHFFFAOYSA-N

Información sobre el gen

human ... CYP1A2(1544)

Aplicación

p-Anisaldehyde may be used as a triplet sensitizer to catalyze the photochemical intermolecular atom-transfer radical addition (ATRA) of haloalkanes onto olefins.[1] It can be used to synthesize 2-(4-methoxybenzylidene)-N-(4-(N-(1-phenyl-1H-pyrazol-5-yl)sulfamoyl)phenyl) hydrazinecarbothioamide.[2] It is also used as a stain for detecting non UV-active substances using thin layer chromatography (TLC).[3]

Pictogramas

Health hazard

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Aquatic Chronic 3 - Repr. 2

Código de clase de almacenamiento

10 - Combustible liquids

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

240.8 °F - closed cup

Punto de inflamabilidad (°C)

116 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Photo?Organocatalysis of Atom?Transfer Radical Additions to Alkenes.
Arceo E
Angewandte Chemie (International Edition in English), 53(45), 12064-12068 (2014)
Synthesis, structural characterization and anticancer evaluation of pyrazole derivatives.
El-Gaby MS
Medicinal Chemistry Research, 27(1), 72-79 (2018)
Qingyao Wu et al.
Nature communications, 12(1), 483-483 (2021-01-22)
Artificial photosynthesis of H2O2 from H2O and O2, as a spotless method, has aroused widespread interest. Up to date, most photocatalysts still suffer from serious salt-deactivated effects with huge consumption of photogenerated charges, which severely limit their wide application. Herein
Stereocontrolled cascade cyclisation of campholenic enol?ether derivatives: en route to vetiver?scented spiroxides.
Ondet P
European Journal of Organic Chemistry, (8), 980-989 (2018)
N Juillet et al.
Plant biology (Stuttgart, Germany), 13(4), 570-575 (2011-06-15)
It has often been proposed that nectarless deceptive orchid species exploit naïve pollinators in search of food before they learn to avoid their flowers, and that intraspecific floral trait polymorphism, often noted in this plant group, could prolong the time

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Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Is there any literature reference regarding its properties?

    1 answer
    1. There are many properties available for p-Anisaldehyde. These are listed in the PROPERTIES section of the product listing. Publications associated with this product can be reviewed at the link below: https://www.sigmaaldrich.com/search/a88107?focus=papers&page=1&perpage=30&sort=relevance&term=a88107&type=citation_search There are a number of p-Anisaldehyde are currently available, in addition to the A88107. A list of these products can be reviewed below: https://www.sigmaaldrich.com/substance/panisaldehyde13615123115 Product SRA1 Anisaldehyde solution, is intended for use in detection of a number of compounds. There is additional information, as well as a number of references cited, in the product datasheet. Please see the link below to review: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/product/documents/106/699/sra1dat.pdf

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