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Merck

919977

Sigma-Aldrich

Bis(trifluorometano)sulfonimida lithium salt

greener alternative

anhydrous, 99.99% trace metals basis

Sinónimos:

Bis(trifluorometilsulfonil)amina lithium salt, Bistrifluorometanosulfonimidato de litio

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About This Item

Fórmula lineal:
CF3SO2NLiSO2CF3
Número de CAS:
Peso molecular:
287.09
Beilstein:
6625414
Número MDL:
Código UNSPSC:
12352111
NACRES:
NA.23
Ensayo:
99.99% trace metals basis
grado:
anhydrous

grado

anhydrous

Nivel de calidad

Ensayo

99.99% trace metals basis

características de los productos alternativos más sostenibles

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sustainability

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mp

234-238 °C (lit.)

aplicaciones

battery manufacturing

categoría alternativa más sostenible

cadena SMILES

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

Clave InChI

QSZMZKBZAYQGRS-UHFFFAOYSA-N

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Descripción general

Lithiumbis(trifluoromethanesulfonyl)imide (LiTFSI) is an anhydrous lithium salt known for its hydrophilic properties and excellent solubility in water. LiTFSI is often used as an electrolyte salt in lithium-ion batteries and other electrochemical energy storage systems. It helps improve the electrolyte′s conductivity, stability, and safety, thereby enhancing the overall performance of the battery. The hydrophilic nature of LiTFSI enables effective ion transport and enhances the overall electrochemical properties of batteriesProperties of LiTFSI:
  • High electrochemical stability
  • High lithium-ion conductivity
  • Thermal stability
  • Hydrophilic nature
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Aplicación

Lithium bis(trifluoromethanesulfonyl)imide can be used as:
  • An additive in the development of dual-functional separator coating materials. These materials are based on covalent organic frameworks (COFs) and are specifically designed for use in high-performance lithium-selenium sulfide batteries. The Li-SeS2 battery achieved outstanding performance in terms of energy storage and stability. It exhibited a specific capacity of 844.6 mA h g-1 at 0.5C and a SeS2 loading of 2 mg cm-2.
  • As an additive in the electrolyte formulation along with polyethylene oxide for the development of solid-state lithium batteries. LiTFSI enhance the ionic conductivity of the PEO-based electrolyte, which is essential for the efficient transport of lithium ions.
  • As a key component in the development of a PEO/LiTFSI-coated polypropylene membrane. This membrane is designed for high-loading lithium–sulfur batteries to enhance battery performance, improve capacity, and extend cycle life.
  • As a component in the electrolyte system along with TEMPOL derivatives. The incorporation of LiTFSI in the electrolyte system enhances the stability and achieves an efficiency of 6.16% in solid-state fiber dye-sensitized solar cells.

Palabra de señalización

Danger

Clasificaciones de peligro

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

Órganos de actuación

Nervous system

Código de clase de almacenamiento

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Qi Chen et al.
Journal of the American Chemical Society, 136(2), 622-625 (2013-12-24)
Hybrid organic/inorganic perovskites (e.g., CH3NH3PbI3) as light absorbers are promising players in the field of third-generation photovoltaics. Here we demonstrate a low-temperature vapor-assisted solution process to construct polycrystalline perovskite thin films with full surface coverage, small surface roughness, and grain
Spherical ordered mesoporous carbon nanoparticles with high porosity for lithium-sulfur batteries.
Jörg Schuster et al.
Angewandte Chemie (International ed. in English), 51(15), 3591-3595 (2012-03-03)
Namyoung Ahn et al.
Journal of the American Chemical Society, 137(27), 8696-8699 (2015-07-01)
High efficiency perovskite solar cells were fabricated reproducibly via Lewis base adduct of lead(II) iodide. PbI2 was dissolved in N,N-dimethyformamide with equimolar N,N-dimethyl sulfoxide (DMSO) and CH3NH3I. Stretching vibration of S═O appeared at 1045 cm(-1) for bare DMSO, which was
Liumin Suo et al.
Nature communications, 4, 1481-1481 (2013-02-14)
Liquid electrolyte plays a key role in commercial lithium-ion batteries to allow conduction of lithium-ion between cathode and anode. Traditionally, taking into account the ionic conductivity, viscosity and dissolubility of lithium salt, the salt concentration in liquid electrolytes is typically

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