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Merck

75991

Sigma-Aldrich

Palladium on activated charcoal

greener alternative

moistened with water, 5% Pd basis (based on dry substance)

Sinónimos:

Pd/C

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About This Item

Fórmula lineal:
Pd
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

form

paste

quality

moistened with water

contains

~50% water as stabilizer

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

5% Pd (based on dry substance)

greener alternative category

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Palladium on activated charcoal can be used as a heterogeneous catalyst:
  • To synthesize methyl esters via oxidative esterification of primary alcohols.
  • In the hydrogenation of phenol to cyclohexanone.
  • For carbonylation of iodoanilines with amines and trimethyl orthoformate to prepare quinazolinones.
  • In the hydrodehalogenation of aromatic halides to form arenes in aqueous media.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Pd/C-catalyzed hydrodehalogenation of aromatic halides in aqueous solutions at room temperature under normal pressure.
Xia C
Catalysis Communications, 5(8), 383-386 (2004)
Oxidative Esterification of Primary Alcohols with a Pd/Bi/Te Catalyst
Uozumi Y and Osako T
Synfacts, 10, 0108-0108 (2014)
Highly selective palladium supported catalyst for hydrogenation of phenol in aqueous phase
Perez Y, et al.
Catalysis Communications, 12, 1071-1074 (2011)
Pd/C as an efficient heterogeneous catalyst for carbonylative four-component synthesis of 4 (3 H)-quinazolinones
Natte K, et al.
Catalysis Science & Technology, 5, 4474-4480 (2015)
Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)

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