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Merck

687553

Sigma-Aldrich

Hydroxymethyl EDOT

95%

Sinónimos:

(2,3-Dihydrothieno[3,4-b][1,4]dioxin-2-yl)methanol, EDT-methanol, Thieno[3,4-b]-1,4-dioxin-2-methanol

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About This Item

Fórmula empírica (notación de Hill):
C7H8O3S
Número de CAS:
Peso molecular:
172.20
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

95%

form

solid

mp

42-46 °C

storage temp.

2-8°C

SMILES string

OCC1COc2cscc2O1

InChI

1S/C7H8O3S/c8-1-5-2-9-6-3-11-4-7(6)10-5/h3-5,8H,1-2H2

InChI key

YFCHAINVYLQVBG-UHFFFAOYSA-N

General description

Hydroxymethyl EDOT (EDT-methanol) is a conjugated polymer that is used as a precursor of ethylenedioxythiophene (EDOT). The hydroxymethyl groups in the EDOT monomers enhance the electro-polymerization in an aqueous solution to form an electro-active hydrophilic polymer.

Application

EDOT derivative useful in preparation of functional electroactive polymers
EDT-methanol can functionalize poly(L-lactic acid) by using organometallic polymerization, which can be used to form biodegradable and conducting macromonomers for biomedical applications. It can be polymerized to form poly(hydroxymethyl EDOT) based films, which may be incorporated with silver nanoparticles to form nanocomposites on polyethylene terephthalate (PET) for flexible plastic devices.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Modification of the electrochemical and electronic properties of electrogenerated poly (3, 4-ethylenedioxythiophene) by hydroxymethyl and oligo (oxyethylene) substituents
Akoudad S and Roncali J
Electrochemical Communications, 2(1), 72-76 (2000)
Perepichka, I.F.; Besbes, M.; Lecillian, E.; Salle, M.; Roncali, J.
Chemistry of Materials, 14, 449-449 (2002)
One pot biocatalytic synthesis of a biodegradable electroactive macromonomer based on 3, 4-ethylenedioxytiophene and poly (l-lactic acid).
da Silva AC, et al.
Materials Science and Engineering, C, 83(1), 35-43 (2018)
Hannah C Goldbach et al.
eLife, 10 (2021-02-02)
Primary visual cortex (V1) in the mouse projects to numerous brain areas, including several secondary visual areas, frontal cortex, and basal ganglia. While it has been demonstrated that optogenetic silencing of V1 strongly impairs visually guided behavior, it is not
Electrogenerated conjugated polymers incorporating a ferrocene-derivatized-(3, 4-ethylenedioxythiophene).
Brisset H, et al.
Electrochemical Communications, 6(3), 249-253 (2004)

Artículos

Conjugated polymers offer charge transport between inorganic, electrically conducting metals and organic, proton-conducting biological systems.

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