656577

1,3-Diisopropylimidazolium chloride

97%

• Sinónimos: N,N′-(Isopropyl)imidazolium chloride
• Fórmula empírica (notación de Hill): C₉H₁₇ClN₂
• Número de CAS: 139143-09-2
• Peso molecular: 188.70
• MDL number: MFCD03840577
• UNSPSC Code: 12352005
• PubChem Substance ID: 24884209
• NACRES: NA.22

Propiedades

• assay: 97%
• form: solid
• reaction suitability: reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 182-186 °C
• greener alternative category: Aligned,
• SMILES string: [Cl-].CC(C)n1cc[n+](c1)C(C)C
• InChI: 1S/C9H17N2.ClH/c1-8(2)10-5-6-11(7-10)9(3)4;/h5-9H,1-4H3;1H/q+1;/p-1
• InChI key: DOFXKPAOJLLPII-UHFFFAOYSA-M

Descripción

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

1,3-Diisopropylimidazolium chloride may be used to prepare:

• 1,3-Diisopropylimidazole-2-thione by reacting with sulfur in the presence of potassium carbonate.
• (C₉H₇)NiCl(1,3-diisopropylimidazol-2- ylidene) by reacting with bis-indenyl nickel-(II).
• Ruthenium N-heterocyclic carbene complexes, which are efficient catalysts for the amidation of primary alcohols and amines.

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves