556084

1-Vinyl cyclohexanol

97%

• Fórmula lineal: H₂C=CHC₆H₁₀OH
• Número de CAS: 1940-19-8
• Peso molecular: 126.20
• EC Number: 217-718-7
• MDL number: MFCD01734994
• UNSPSC Code: 12352100
• PubChem Substance ID: 24879518
• NACRES: NA.22

Propiedades

• assay: 97%
• refractive index: n20/D 1.478 (lit.)
• bp: 74 °C/19 mmHg (lit.)
• density: 0.942 g/mL at 25 °C (lit.)
• SMILES string: OC1(CCCCC1)C=C
• InChI: 1S/C8H14O/c1-2-8(9)6-4-3-5-7-8/h2,9H,1,3-7H2
• InChI key: ZXKHOVDDJMJXQP-UHFFFAOYSA-N

Descripción

General description

1-Vinyl cyclohexanol, also known as 1-vinyl-1-cyclohexanol, is a tertiary allylic alcohol. It can be synthesized from cyclohexanone and vinyl chloride. It can undergo transition-metal-free tandem allylic borylation in the presence of B₂pin [bis(pinacolato)diboron], Cs₂CO₃, THF and MeOH to yield triborated product. Pd-fullerite catalysts have been prepared which effectively catalyzes the hydrogenation of 1-ethynyl-1-cyclohexanol to 1-vinyl-1-cyclohexanol.

Application

1-Vinyl cyclohexanol may be used to synthesize:

• 1-vinyl-1-cyclohexene
• 1-vinyl-1-cyclohexylacrylate
• cyclohexylideneacetaldehyde

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 158.0 °F - closed cup
• flash_point_c: 70 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter