552844

3-Amino-6-bromopyridine

97%

• Fórmula empírica (notación de Hill): C₅H₅BrN₂
• Número de CAS: 13534-97-9
• Peso molecular: 173.01
• MDL number: MFCD01646116
• UNSPSC Code: 12352100
• PubChem Substance ID: 24879291
• NACRES: NA.22

Propiedades

• assay: 97%
• form: solid
• mp: 74-76 °C (lit.)
• SMILES string: Nc1ccc(Br)nc1
• InChI: 1S/C5H5BrN2/c6-5-2-1-4(7)3-8-5/h1-3H,7H2
• InChI key: XTHKRYHULUJQHN-UHFFFAOYSA-N

Descripción

General description

3-Amino-6-bromopyridine can be synthesized via bromination of 3-aminopyridine using N-bromosuccinimide in acetonitrile.

Application

3-Amino-6-bromopyridine may undergo polymerization via Buchwald–Hartwig amination in the presence of sodium tert-butoxide and XPhos(2-dicyclohexylphosphino-2′,4′,6′-triisopropylbiphenyl) ligand yielding para-linked and meta-linked polyaminopyridines.

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves