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517925

Sigma-Aldrich

4′-Methylpropiophenone

90%, technical grade

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About This Item

Fórmula lineal:
CH3C6H4COC2H5
Número de CAS:
5337-93-9
Peso molecular:
148.20
EC Number:
226-267-5
MDL number:
MFCD00009312
UNSPSC Code:
12352100
PubChem Substance ID:
24873986
NACRES:
NA.22

grade

technical grade

assay

90%

refractive index

n20/D 1.528 (lit.)

bp

238-239 °C (lit.)

density

0.993 g/mL at 25 °C (lit.)

SMILES string

CCC(=O)c1ccc(C)cc1

InChI

1S/C10H12O/c1-3-10(11)9-6-4-8(2)5-7-9/h4-7H,3H2,1-2H3

InChI key

PATYHUUYADUHQS-UHFFFAOYSA-N

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Application

4′-Methylpropiophenone can be used as a building block to synthesize:
  • N





  • -(4-Chlorophenyl)-N′-[1-(4-methylphenyl)propyl]urea as a potential CRAC channel inhibitor.
  • Mono and trinuclear cobaloxime/organocobaloxime complexes, which are used as efficient catalysts for the synthesis of cyclic carbonates.
  • Tolperisone (TOL) via acid-catalyzed reaction with piperidine hydrochloride and 1,2-dioxolane.

Other Notes

Remainder 3′-methylpropiophenone

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

228.2 °F - closed cup

flash_point_c

109.00 °C - closed cup

ppe

Eyeshields, Gloves

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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TLC-densitometric determination of tolperisone and its impurities 4-methylpropiophenone and piperidine in pharmaceutical preparations
Hubicka U, et al.
Journal of Liquid Chromatography and Related Technologies, 35(10), 1325-1335 (2012)
Ketone synthesized cobaloxime/organocobaloxime catalysts for cyclic carbonate synthesis from CO2 and epoxides: Characterization and electrochemistry
Kilic A, et al.
Journal of Organometallic Chemistry, 767, 150-159 (2014)
Paul I Dargan et al.
Drug testing and analysis, 3(7-8), 454-463 (2011-07-15)
Mephedrone (4-methylmethcathinone) is a synthetic cathinone that is used as a recreational drug. It has been available since 2007 but its availability and use increased significantly during 2009 and 2010. In this review article we will summarize the available literature
Alkaloid induced asymmetric electrocarboxylation of 4-methylpropiophenone.
Zhao SF, et al.
Tetrahedron Letters, 52(21), 2702-2705 (2011)
V Karunakaran et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 128, 1-14 (2014-03-25)
Combined experimental and theoretical studies have been performed on the structure and vibrational spectra (IR and Raman spectra) of 4'-methylpropiophenone (MPP). The FT-IR and FT-Raman spectra of 4'-methylpropiophenone (MPP) have been recorded in the region 4000-400 cm(-1) and 3500-100 cm(-1)
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