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46210

Sigma-Aldrich

(+)-Fenchone

purum, ≥98.0% (sum of enantiomers, GC)

Sinónimos:

(+)-1,3,3-Trimethyl-2-norbornanone, (1S)-1,3,3-Trimethylbicyclo[2.2.1]heptan-2-one

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About This Item

Fórmula empírica (notación de Hill):
C10H16O
Número de CAS:
4695-62-9
Peso molecular:
152.23
Beilstein/REAXYS Number:
2206555
EC Number:
225-160-0
MDL number:
MFCD00070689
UNSPSC Code:
12352212
PubChem Substance ID:
57650740
NACRES:
NA.22

grade

purum

assay

≥98.0% (sum of enantiomers, GC)

optical activity

[α]20/D +60±3°, neat

refractive index

n20/D 1.463

bp

63-65 °C/13 mmHg (lit.)

mp

5-7 °C (lit.)

density

0.945 g/mL at 20 °C (lit.)

SMILES string

CC1(C)[C@@H]2CC[C@@](C)(C2)C1=O

InChI

1S/C10H16O/c1-9(2)7-4-5-10(3,6-7)8(9)11/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

InChI key

LHXDLQBQYFFVNW-XCBNKYQSSA-N

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Storage Class

10 - Combustible liquids

wgk_germany

WGK 2

flash_point_f

150.8 °F - closed cup

flash_point_c

66 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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B Simándi et al.
Journal of agricultural and food chemistry, 47(4), 1635-1640 (1999-11-24)
Ground fennel seeds were extracted with supercritical carbon dioxide. Small-scale subsequent extractions of the same sample showed that the composition of volatile compounds was changed with the extension of extraction time and only principal volatile components (limonene, fenchone, methylchavicol, and
Giovanna Longhi et al.
The journal of physical chemistry. A, 110(15), 4958-4968 (2006-04-14)
We report and discuss the infrared (IR) vibrational circular dichroism (VCD) spectra of the enantiomeric pairs of the olefin derivatives of fenchone (1,3,3-trimethyl-2-methylenebicyclo[2.2.1]heptane) and camphor (1,7,7-trimethyl-2-methylenebicyclo[2.2.1]heptane), respectively, together with those of the parent molecules. The VCD spectra were taken in
Dirk W Lachenmeier et al.
Journal of agricultural and food chemistry, 56(9), 3073-3081 (2008-04-19)
Thirteen samples of authentic absinthe dating from the preban era (i.e., prior to 1915) were analyzed for parameters that were hypothesized as contributing to the toxicity of the spirit, including naturally occurring herbal essences (thujone, pinocamphone, fenchone), methanol, higher alcohols
Hua-Zhen Qin et al.
Zhong yao cai = Zhongyaocai = Journal of Chinese medicinal materials, 34(12), 1897-1899 (2012-04-17)
To study the components of volatile oil of Alpinia henryi. The volatile oil was extracted by steam distillation method,used gaseous phase-mass spectrum combination method (GC-MS) to analyze the components of volatile oil. 58 kinds of components were isolated, among them
Philip C Bulman Page et al.
The Journal of organic chemistry, 67(22), 7787-7796 (2002-10-26)
The first two stable enantiomerically pure chiral N-H oxaziridines, derived from camphor and fenchone, are shown to act as electrophilic sources of nitrogen upon reaction with various carbon nucleophiles. Nitrogen is transferred, together with the camphor/fenchone unit, when deprotonated esters
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