423602

Ethyl cis-3-iodoacrylate

98%

• Fórmula lineal: ICH=CHCO₂C₂H₅
• Número de CAS: 31930-36-6
• Peso molecular: 226.01
• MDL number: MFCD00209584
• UNSPSC Code: 12352100
• PubChem Substance ID: 24866512
• NACRES: NA.22

Propiedades

• Quality Level: 200
• assay: 98%
• form: liquid
• refractive index: n20/D 1.533 (lit.)
• bp: 85 °C/20 mmHg (lit.)
• density: 1.765 g/mL at 25 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: [H]\C(I)=C(/[H])C(=O)OCC
• InChI: 1S/C5H7IO2/c1-2-8-5(7)3-4-6/h3-4H,2H2,1H3/b4-3-
• InChI key: AELYFQSZXFFNGP-ARJAWSKDSA-N

Descripción

General description

Ethyl cis-3-iodoacrylate (cis-ethyl-β-iodoacrylate, ethyl (Z)-β-iodoacrylate) is Z-vinyl iodide derivative. It is reported to be prepared from ethyl propiolate by treating with sodium iodide. Its Suzuki coupling reaction with cyclic vinyl boronic acids has been studied.

Application

Ethyl cis-3-iodoacrylate may be used in the synthesis of the following:

• vinyl sulfides
• (Z)-1-iodohept-1-en-3-ol
• (E)-1-iodohept-1-en-3-ol
• (Z)-β-iodoacrolein
• 6-oxo-M₁Guo

Información de seguridad

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 210.2 °F - closed cup
• flash_point_c: 99 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter