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Merck

413321

Sigma-Aldrich

Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane

98%

Sinónimos:

[2-(3,4-Epoxycyclohexyl)ethyl]trimethoxysilane, 2-(7-Oxabicyclo[4.1.0]hept-3-yl)ethyl-trimethoxysilane, 3-(2-Trimethoxysilylethyl)cyclohexene oxide

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About This Item

Fórmula empírica (notación de Hill):
C11H22O4Si
Número de CAS:
Peso molecular:
246.38
Beilstein/REAXYS Number:
8980119
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

assay

98%

form

liquid

refractive index

n20/D 1.451 (lit.)

bp

310 °C (lit.)

density

1.065 g/mL at 25 °C (lit.)

SMILES string

CO[Si](CCC1CCC2OC2C1)(OC)OC

InChI

1S/C11H22O4Si/c1-12-16(13-2,14-3)7-6-9-4-5-10-11(8-9)15-10/h9-11H,4-8H2,1-3H3

InChI key

DQZNLOXENNXVAD-UHFFFAOYSA-N

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Application

Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane can be used as a silane based coupling agent to functionalize a variety of substrates. It modifies the surface to improve the dispersion of nanoparticles. It can be used as an adhesion promoter by treating the precursor material with epoxy silanes.
Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane was used as an adhesion promoter during the fabrication of:
  • a photoacid generator activated by two photon excitation.
  • nanoscale polymeric structures (width: 65 nm) using 520 nm femtosecond pulse excitation.

Trimethoxy[2-(7-oxabicyclo[4.1.0]hept-3-yl)ethyl]silane may be used as a precursor to form SiCOH film via sol-gel. The silane may be used to functionalize alumina nanoparticles towards the fabrication of polyamide 12/alumina nanocomposites. 4 Basalt fibers were functionalized with this silane and its consequent effect on the fabrication of basalt fiber–epoxidized vegetable oil matrix composite materials was analyzed.

Features and Benefits

Ring epoxide more reactive than glycidoxypropyl systems.

pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Aquatic Chronic 3 - Carc. 2 - Muta. 2 - Skin Sens. 1B

Storage Class

10 - Combustible liquids

wgk_germany

WGK 2

flash_point_f

276.8 °F - Pensky-Martens closed cup

flash_point_c

136 °C - Pensky-Martens closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


Certificados de análisis (COA)

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Visite la Librería de documentos

65 nm feature sizes using visible wavelength 3-D multiphoton lithography.
Optics Express, 15(6), 3426-3436 (2007)
X J Huang et al.
Se pu = Chinese journal of chromatography, 19(6), 485-488 (2003-01-28)
A new silane coupling agent, beta-(3,4-epoxycyclohexyl)ethyltrimethoxy silane, was for the firsty time used to react with octanol, then the intermediate product was coupled onto porous silica to obtain a novel bonded phase for reversed-phase high performance liquid chromatography (RP-HPLC). Characterization
Design and application of high-sensitivity two-photon initiators for three-dimensional microfabrication.
Kuebler SM.
Journal of Photochemistry and Photobiology A: Chemistry, 158(2-3), 163-170 (2003)
Effect of silane coupling agents on basalt fiber?epoxidized vegetable oil matrix composite materials analyzed by the single fiber fragmentation technique.
Polymer Composites (2014)
PEBAXTM-Silanized Al2O3Composite. Synthesis and Characterization.
Lara-Estevez JCI, et al.
Open Journal of Polymer Chemistry, 2(02), 63-63 (2012)

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