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Sigma-Aldrich

1,1′-Azobis(cyclohexanecarbonitrile)

1,1′-Azobis(cyclohexanecarbonitrile)

98%

Sinónimos:

1,1′-Azobis(cyanocyclohexane), ACHN

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About This Item

Fórmula lineal:
NCC6H10N=NC6H10CN
Número de CAS:
2094-98-6
Peso molecular:
244.34
Beilstein:
960744
Número CE:
218-254-8
Número MDL:
MFCD00046334
Código UNSPSC:
12162002
ID de la sustancia en PubChem:
24863728
NACRES:
NA.23
En este momento no podemos mostrarle ni los precios ni la disponibilidad

Nivel de calidad

200

Ensayo

98%

Formulario

solid

mp

114-118 °C (lit.)

temp. de almacenamiento

2-8°C

cadena SMILES

N#CC1(CCCCC1)\N=N\C2(CCCCC2)C#N

InChI

1S/C14H20N4/c15-11-13(7-3-1-4-8-13)17-18-14(12-16)9-5-2-6-10-14/h1-10H2/b18-17+

Clave InChI

KYIKRXIYLAGAKQ-ISLYRVAYSA-N

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Descripción general

1,1′-Azobis(cyclohexanecarbonitrile) (AHCN) is a thermally stable initiator that can be used in free-radical polymerization. It is soluble in a variety of solvents such as methanol, dimethylformamide (DMF), etc.[1][2]

Aplicación

A more efficient radical initiator than AIBN has been employed to initiate primary radical reactions.[3]

Pictogramas

FlameExclamation mark
GHS02,GHS07

Palabra de señalización

Danger

Frases de peligro

H242,H315,H319,H335

Clasificaciones de peligro

Eye Irrit. 2 - Self-react. D - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

5.2 - Organic peroxides and self-reacting hazardous materials

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
MKCW8577
MKCS6689
MKCQ0071
MKCH5807
MKCJ6952

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1, 11 AZOBIS (CYCLOHEXANECARBONITRILE) INITIATED COPOLYMERIZATION OF ACRYLONITRILE COPOLYMERS AND THEIR CHARACTERIZATION
Sridevi S, et al.
Chem, 2(5), 61-61 (2009)
Youfeng Yue et al.
Nature communications, 9(1), 3234-3234 (2018-08-15)
Energy conversion of light into mechanical work is of fundamental interest in applications. In particular, diligent molecular design on nanoscale, in order to achieve efficient photomechanical effects on macroscopic scale, has become one of the most interesting study topics. Here
The Journal of Organic Chemistry, 52, 2958-2958 (1987)
Iron-Based ICAR ATRP of Styrene with ppm Amounts of FeIIIBr3 and 1, 1′-Azobis (cyclohexanecarbonitrile)
Mukumoto K, et al.
ACS Macro Letters, 1(5), 599-602 (2012)
Mi Hee Lim
Nature protocols, 2(2), 408-415 (2007-04-05)
A procedure for the preparation of a copper(II) complex (CuFL) as a fluorescent nitric oxide (NO) detector is described. The fluorescein-based ligand FL can be synthesized in seven reaction steps (overall yield approximately 20%), typically requiring a total time of
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1 Review This action will navigate to reviews.

Questions

  1. Is ACHN sufficiently soluble in CCl4? Specifically, can it replace AIBN in the bromination reaction of 4'-(p-Tolyl)-2,2':6',2''-terpyridine with N-Bromosuccinimide? According to Inorg Chem 2003 42, 2908-2918.

    1 answer

    1. The solubility of this product in CCL4 as well as the capability of replacing AIBN in the bromination reaction, has not been determined. It may be helpful to review the following literature:
      check the chemical literature on this compound through (for example) PubChem: https://pubchem.ncbi.nlm.nih.gov/compound/1_1_-Azobis_cyclohexanecarbonitrile

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Reviews

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  1. Hyderabad, India
    • Review 1
    • Vote 1
    4 out of 5 stars.

    A better radical initiator than AIBN

    ACHN is a good radical initiator with less decomposition temperature compared to AIBN, can you use at temperatures less than required for AIBN.

    Helpful?

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