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Merck

377074

Sigma-Aldrich

Pentafluorophenyl trifluoroacetate

98%, for peptide synthesis

Sinónimos:

Trifluoroacetic acid pentafluorophenyl ester

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About This Item

Fórmula lineal:
CF3CO2C6F5
Número de CAS:
Peso molecular:
280.07
Beilstein:
2003848
Número MDL:
Código UNSPSC:
12352101
ID de la sustancia en PubChem:
NACRES:
NA.22
En este momento no podemos mostrarle ni los precios ni la disponibilidad

Nombre del producto

Pentafluorophenyl trifluoroacetate, 98%

Nivel de calidad

Ensayo

98%

Formulario

liquid

índice de refracción

n20/D 1.368 (lit.)

bp

122-123 °C (lit.)

densidad

1.63 g/mL at 25 °C (lit.)

aplicaciones

peptide synthesis

grupo funcional

ester
fluoro

cadena SMILES

Fc1c(F)c(F)c(OC(=O)C(F)(F)F)c(F)c1F

InChI

1S/C8F8O2/c9-1-2(10)4(12)6(5(13)3(1)11)18-7(17)8(14,15)16

Clave InChI

VCQURUZYYSOUHP-UHFFFAOYSA-N

Aplicación

Pentafluorophenyl trifluoroacetate can be used:
  • In the esterification of 2′-carboxyrhodamine dye to form pentafluorophenyl ester as a single isomer.[1]
  • As an acylating agent and a coupling agent for the peptide-type coupling of N-substituted glycine oligomers.[2]
  • In the synthesis of pentafluorophenyl thiophene-3-acetate (PFPTA) by reacting with 3-thiopheneacetic acid.[3]

Otras notas

may contain a small amount of pentafluorophenol

Pictogramas

FlameExclamation mark

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Respiratory system

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

125.6 °F - closed cup

Punto de inflamabilidad (°C)

52 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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