The journal of physical chemistry. A, 124(22), 4471-4483 (2020-05-14)
Parahydrogen (pH2) quantum solids are excellent matrix isolation hosts for studying the rovibrational dynamics and nuclear spin conversion (NSC) kinetics of molecules containing indistinguishable nuclei with nonzero spin. The relatively slow NSC kinetics of propyne (CH3CCH) isolated in solid pH2
Physical chemistry chemical physics : PCCP, 14(12), 4230-4235 (2012-02-18)
Two-body decomposition processes of methylacetylene (CH(3)CCH) and its isotopomer methyl-d(3)-acetylene (CD(3)CCH) in intense laser fields (790 nm, 40 fs, 5.0 × 10(13) W cm(-2)) are investigated by the coincidence momentum imaging (CMI). In methyl-d(3)-acetylene, a total of six decomposition pathways
A group of beta-phenylethylidenehydrazines possessing a variety of substituents (Me, OMe, Cl, F, and CF(3)) at the ortho-, meta-, or para-positions of the phenyl ring, in conjunction with either a N-bis-(2-propynyl) or a N-mono-(2-propynyl) moiety, were synthesized and compared to
Journal of the American Chemical Society, 134(21), 8770-8773 (2012-05-19)
The palladium-catalyzed cross-coupling of chiral propargyl acetates and allyl boronates delivers chiral 1,5-enynes with excellent levels of chirality transfer and can be applied across a broad range of substrates.
A supported catalyst and a catalytic process have been developed for the conversion of carbgas (CO2 + (100 ppm) H2O + 1% H2) as a renewable source of energy and as a measure for the control of carbon dioxide --
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