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295183

Sigma-Aldrich

Cyclopropane

≥99%

Sinónimos:

Trimethylene (6CI)

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About This Item

Fórmula empírica (notación de Hill):
C3H6
Número de CAS:
75-19-4
Peso molecular:
42.08
EC Number:
200-847-8
MDL number:
MFCD00001268
UNSPSC Code:
12142100
PubChem Substance ID:
24857764
NACRES:
NA.22
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vapor density

1.45 (vs air)

Quality Level

100

assay

≥99%

autoignition temp.

928 °F

expl. lim.

10.4 %

bp

−33 °C (lit.)

mp

−128 °C (lit.)

SMILES string

C1CC1

InChI

1S/C3H6/c1-2-3-1/h1-3H2

InChI key

LVZWSLJZHVFIQJ-UHFFFAOYSA-N

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Application

Cyclopropane has been used as the pseudo-π unsaturated hydrocarbon prototype to study the rotational spectrum of its complex formed with chlorine monofluoride and the similarity of this complex with isotopomers.[1]

Packaging

Supplied in a Sure/Pac™ cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.

Compatible with the following:

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

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Hose adapter, brass

regulator

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Z513539

Aldrich® mini gas regulator, brass body

pictograms

FlameGas cylinder
GHS02,GHS04

signalword

Danger

hcodes

H220,H280

Hazard Classifications

Flam. Gas 1 - Press. Gas Liquefied gas

Storage Class

2A - Gases

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)

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Certificados de análisis (COA)

Lot/Batch Number
SHBP7402
SHBH9047
STBC3584V
SHBB6363V
STBC3318V

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Kristyna Pluhackova et al.
BMC biology, 19(1), 4-4 (2021-01-15)
Lipid-protein interactions stabilize protein oligomers, shape their structure, and modulate their function. Whereas in vitro experiments already account for the functional importance of lipids by using natural lipid extracts, in silico methods lack behind by embedding proteins in single component
Pedro S Coelho et al.
Science (New York, N.Y.), 339(6117), 307-310 (2012-12-22)
Transition metal-catalyzed transfers of carbenes, nitrenes, and oxenes are powerful methods for functionalizing C=C and C-H bonds. Nature has evolved a diverse toolbox for oxene transfers, as exemplified by the myriad monooxygenation reactions catalyzed by cytochrome P450 enzymes. The isoelectronic
A pseudo-? analogue of a Mulliken b?. a? type complex: The rotational spectrum of cyclopropane?chlorine monofluoride.
Holloway JH & Legon AC.
J. Chem. Soc., Faraday Trans., 93(3), 373-378 (1997)
Lewis acid catalyzed formal intramolecular [3+2] cross-cycloaddition of cyclopropane 1,1-diesters with alkenes: general and efficient strategy for construction of bridged [n.2.1] carbocyclic skeletons.
Wenju Zhu et al.
Angewandte Chemie (International ed. in English), 52(7), 2032-2037 (2013-01-12)
Yoshihiro Oonishi et al.
Angewandte Chemie (International ed. in English), 51(29), 7305-7308 (2012-06-29)
Giving direction: An C sp 3-H bond activation directed by a rhodacycle intermediate has been found to occur in a Rh(I)-catalyzed reaction between an allene moiety having a tert-butyl substituent, and tethered alkynes. Cyclic compounds containing a cyclopropane ring were obtained in
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