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439290

Sigma-Aldrich

2,6-Dichloro-1-fluoropyridinium tetrafluoroborate

97%

Synonym(s):

1-Fluoro-2,6-dichloropyridinium tetrafluoroborate, 2,6-Dichloro-1-fluoropyridin-1-ium, 2,6-Dichloro-1-fluoropyridinium tetrafluoroborate(1-), N-Fluoro-2,6-dichloropyridinium tetrafluoroborate, tetrafluoroboranuide

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About This Item

Empirical Formula (Hill Notation):
C5H3BCl2F5N
CAS Number:
140623-89-8
Molecular Weight:
253.79
EC Number:
427-400-1
MDL number:
MFCD00153157
UNSPSC Code:
12352100
PubChem Substance ID:
24867496
NACRES:
NA.22

Assay

97%

mp

212-215 °C (lit.)

functional group

chloro

SMILES string

F[B-](F)(F)F.F[n+]1c(Cl)cccc1Cl

InChI

1S/C5H3Cl2FN.BF4/c6-4-2-1-3-5(7)9(4)8;2-1(3,4)5/h1-3H;/q+1;-1

InChI key

JVYBYXWHPIEUOT-UHFFFAOYSA-N

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General description

2,6-Dichloro-1-fluoropyridinium tetrafluoroborate is widely employed as fluorinating reagent in various reactions.

Application

2,6-Dichloro-1-fluoropyridinium tetrafluoroborate may be employed for the regioselective fluorination of fluorene.

Signal Word

Danger

Hazard Statements

H302,H314,H317,H410

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT5205
MKCV0489
MKCR4237
MKCQ4481
MKCP2055

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Fluorination of fluorene, dibenzofuran and their open analogues with caesium fluoroxysulfate and related fluorinating reagents.
Iskra J, et al.
Collection of Czechoslovak Chemical Communications, 73(12), 1671-1680 (2008)
Electrophilic NF Fluorinating Agents.
G. Sankar Lal et al.
Chemical reviews, 96(5), 1737-1756 (1996-08-01)
Oriol Planas et al.
Science (New York, N.Y.), 367(6475), 313-317 (2020-01-18)
Bismuth catalysis has traditionally relied on the Lewis acidic properties of the element in a fixed oxidation state. In this paper, we report a series of bismuth complexes that can undergo oxidative addition, reductive elimination, and transmetallation in a manner

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