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290572

Tris(pentafluorophenyl)phosphine

Name: Tris(pentafluorophenyl)phosphine
Brand: ALDRICH

97%

Synonym(s):

Tris(perfluorophenyl)phosphine

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About This Item

Linear Formula:

(C₆F₅)₃P

CAS Number:

1259-35-4

Molecular Weight:

532.14

Beilstein:

773243

EC Number:

215-021-2

MDL number:

MFCD00079654

UNSPSC Code:

12352101

PubChem Substance ID:

24857475

NACRES:

NA.22

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Quality Level

200

Assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

108-110 °C (lit.)

functional group

phosphine

SMILES string

Fc1c(F)c(F)c(P(c2c(F)c(F)c(F)c(F)c2F)c3c(F)c(F)c(F)c(F)c3F)c(F)c1F

InChI

1S/C18F15P/c19-1-4(22)10(28)16(11(29)5(1)23)34(17-12(30)6(24)2(20)7(25)13(17)31)18-14(32)8(26)3(21)9(27)15(18)33

InChI key

FQLSDFNKTNBQLC-UHFFFAOYSA-N

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Pictograms

GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Precautionary Statements

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo species.

Rui Zhang et al.

Journal of the American Chemical Society, 127(18), 6573-6582 (2005-05-05)

Porphyrin-manganese(V)-oxo and porphyrin-manganese(IV)-oxo species were produced in organic solvents by laser flash photolysis (LFP) of the corresponding porphyrin-manganese(III) perchlorate and chlorate complexes, respectively, permitting direct kinetic studies. The porphyrin systems studied were 5,10,15,20-tetraphenylporphyrin (TPP), 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin (TPFPP), and 5,10,15,20-tetrakis(4-methylpyridinium)porphyrin (TMPyP). The

Structure of tris(pentafluorophenyl)phosphine.

A Karipides et al.

Acta crystallographica. Section C, Crystal structure communications, 45 ( Pt 11), 1743-1745 (1989-11-15)

C18F15P, Mr = 532.1, monoclinic, P2(1)/c, a = 7.194 (2), b = 17.930 (4), c = 13.834 (2) A, beta = 94.29 (2) degrees, V = 1779 A3, Z = 4, Dm = 2.00, Dx = 1.99 g cm-3, lambda(Mo

Probing bare high-valent transition oxo-metal complexes: an electrospray ionization Fourier transform ion cyclotron resonance study of reactive intermediates.

Barbara Chiavarino et al.

European journal of mass spectrometry (Chichester, England), 16(3), 407-414 (2008-01-01)

Functional models of the Compound I intermediate of monooxygenase heme enzymes, namely [(TPFPP)(*+)Fe(IV)=O](+) and [(TPFPP)Mn(V)=O](+) (TPFPP = meso-tetrakis (pentafluorophenyl)porphyrinato dianion), are obtained as bare species by electrospray ionization from solutions of appropriate precursors and their reactivity is investigated in the

Key Documents

Tris(pentafluorophenyl)phosphine

97%

About This Item

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Properties

Quality Level

Assay

form

reaction suitability

mp

functional group

SMILES string

InChI

InChI key

Safety Information

Pictograms

Signal Word

Hazard Statements

Precautionary Statements

Hazard Classifications

Target Organs

Storage Class Code

WGK

Flash Point(F)

Flash Point(C)

Personal Protective Equipment

Documentation

Certificates of Analysis (COA)

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