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239321

Sigma-Aldrich

Sulfite de sodium

ACS reagent, ≥98.0%

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About This Item

Formule linéaire :
Na2SO3
Numéro CAS:
7757-83-7
Poids moléculaire :
126.04
Numéro CE :
231-821-4
Numéro MDL:
MFCD00003503
Code UNSPSC :
12352302
ID de substance PubChem :
329752528
Nomenclature NACRES :
NA.21
Essai:
≥98.0%
Qualité:
ACS reagent
Forme:
powder or crystals
Solubilité:
water: soluble 126 g/L at 20 °C
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Qualité

ACS reagent

Niveau de qualité

200

Agence

suitable for SM 5210

Essai

≥98.0%

Forme

powder or crystals

Impuretés

Free acid, passes test
≤0.005% insolubles
≤0.03 meq/g Titr. free base

pH

9.0-10.5 (25 °C, 126 g/L)

Solubilité

water: soluble 126 g/L at 20 °C

Traces d'anions

chloride (Cl-): ≤0.02%

Traces de cations

Fe: ≤0.001%
heavy metals (as Pb): ≤0.001%

Chaîne SMILES 

[Na+].[Na+].[O-]S([O-])=O

InChI

1S/2Na.H2O3S/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2

Clé InChI

GEHJYWRUCIMESM-UHFFFAOYSA-L

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Description générale

Sodium sulfite is a water-soluble inorganic salt that is commonly used as a reducing agent. It is also used for sulfonation and sulfomethylation reactions. Additionally, it is used in the textile industry as a bleaching, de-sulfurizing, and dechlorinating agent. As an oxygen and free chlorine scavenger, Na2SO3 is employed in the water treatment process. Sodium sulfite participates in the purification and isolation of aldehydes and ketones by forming adducts with them. Other uses include the production of sodium thiosulfate, detergents, and dyes.

Application

Sodium sulfite can be used:
  • As a reducing agent in the hydroxylation of arylboronic acids and arylboronic esters into corresponding phenols.
  • In the transformation of α-amino alcohol methanesulfonate hydrochlorides to sodium α-amino alkanesulfonates.
  • As a SO2 precursor in the multigram synthesis of DABCO·(SO2)2 abbreviated as DABSO.

Code de la classe de stockage

13 - Non Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

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Certificats d'analyse (COA)

Lot/Batch Number
0000413682
0000413682
MKCX1378
0000382205
0000382205

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Consulter la Bibliothèque de documents

Reaction kinetics of sodium sulfite oxidation by the rapid-mixing method.
Barron CH and O'Hern HA.
Chemical Engineering Science, 21(5), 397-404 (1966)
New plasticizers for wheat gluten films.
Irissin-Mangata J, et al.
European Polymer Journal, 37(8), 1533-1541 (2001)
Amber R Boles et al.
Biotechnology and bioengineering, 109(3), 637-646 (2011-10-22)
A novel sulfur-utilizing perchlorate reducing bacterial consortium successfully treated perchlorate (ClO₄⁻) in prior batch and bench-scale packed bed reactor (PBR) studies. This study examined the scale up of this process for treatment of water from a ClO ₄⁻ and RDX contaminated
Yisu Han et al.
ACS chemical biology, 14(4), 619-635 (2019-03-09)
APEX is an engineered peroxidase that catalyzes the oxidation of a wide range of substrates, facilitating its use in a variety of applications from subcellular staining for electron microscopy to proximity biotinylation for spatial proteomics and transcriptomics. To further advance
Jingang Wang et al.
Chemosphere, 91(3), 351-357 (2012-12-26)
This paper presents a simple, easy and reliable method for determination of EDTA (ethylenediaminetetraacetic acid) in aqueous system. Using EDTA chelating with ferric irons, an excessive amount of Fe(3+) was added to EDTA solution, and Fe(3+) in excess was reduced
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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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