431648

Sodium sulfide nonahydrate

≥99.99% trace metals basis

• Synonyme(s) : Disodium sulfide nonahydrate, Sodium sulfide enneahydrate
• Formule linéaire : Na₂S·9H₂O
• Numéro CAS: 1313-84-4
• Poids moléculaire : 240.18
• Numéro CE : 215-211-5
• Numéro MDL: MFCD00149184
• Code UNSPSC : 12352300
• ID de substance PubChem : 24867038
• Nomenclature NACRES : NA.23

Propriétés

• Pureté: ≥99.99% trace metals basis
• Forme: crystals and lumps
• Pertinence de la réaction: reagent type: catalyst; core: sodium
• Impuretés: <100 ppm total metallic impurities
• Traces d'anions: SO₃^2- and S₂O₃^2-: ≤0.1%
• Traces de cations: Fe:, passes test; NH₄⁺: ≤0.005%
• Température de stockage: 2-8°C
• Chaîne SMILES: O.O.O.O.O.O.O.O.O.[Na]S[Na]
• InChI: 1S/2Na.9H2O.S/h;;9*1H2;
• Clé InChI: UIINQVYGFKNSPA-UHFFFAOYSA-N

Description

Description générale

Sodium sulfide nonahydrate is a chemical compound with the formula Na₂S-H₂O. It is a white to yellow hygroscopic solid that is highly soluble in water and has a strong, unpleasant odor. Sodium sulfide nonahydrate is typically made by dissolving elemental sulfur in a solution of sodium hydroxide, which leads to the formation of sodium sulfide. The nonahydrate form of the compound is formed by adding excess water to the solution, which leads to the formation of a crystalline solid with nine molecules of water per molecule of sodium sulfide. Sodium sulfide nonahydrate is often used as a reducing agent in chemical reactions as well as a flotation agent in the mining industry. It is also used in the production of dyes, pigments, and other chemicals.

Application

Sodium sulfide nonahydrate (Na₂S.9H₂O) can be reacted with α,ω-dibromo and/or α,ω-dichloroalkane for the synthesis of polyalkylene sulfide. It can be used as a reducing agent for the removal of nitrogen oxide from the exhaust gas. Na₂S.9H₂O can also be used as an inexpensive sulfur source for the synthesis of heterocyclic thiochromes.

Informations sur la sécurité

• Pictogrammes: GHS06,GHS05,GHS09
• Mention d'avertissement: Danger
• Mentions de danger: H302,H311,H314,H410
• Conseils de prudence: P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
• Code de la classe de stockage: 6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges