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935972

Sigma-Aldrich

Sodium hexafluorophosphate solution

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greener alternative

in ethylene carbonate, dimethylcarbonate, and ethylmethylcarbonate, 1.0 M NaPF6 in EC/DMC/EMC=1:1:1 (v/v/v), battery grade

Synonyme(s) :

1.0 M NaPF6 in EC/DMC/EMC

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About This Item

Numéro CAS:
Code UNSPSC :
12352600

Qualité

battery grade

Niveau de qualité

Forme

solution

Caractéristiques du produit alternatif plus écologique

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Concentration

0.95-1.10 M (NaPF6)

Impuretés

≤100 ppm Acid
≤100.0 ppm H2O

Application(s)

battery manufacturing

Autre catégorie plus écologique

Description générale

Sodium hexafluorophosphate (NaPF6) solution in ethylene carbonate (EC), dimethylcarbonate (DMC), and ethylmethylcarbonate (EMC) is a clear solution of battery grade sodium hexafluorophosphate dissolved in a a ternary mixture of EC/DMC/EMC (1:1:1) (v/v/v). We offer this with a superior quality suitable for battery research with low water and acid impurities.
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Application

The main application of 1.0 M NaPF6 in EC/DMC/EMC=1:1:1 (v/v/v) is as an electrolyte in sodium-ion batteries (NIBs). The solvent blend has a high dielectric constant, which allows for effective dissolution of the electrolyte salt and results in high ionic conductivity. The fraction of ethylene carbonate (EC) helps to form a stable, conductive solid electrolyte interphase (SEI) with many cathode anode materials. Ethyl methyl carbonate (EMC) and dimethyl carbonate (DMC) have lower viscosities and melting points than EC, and when mixed with EC result in an electrolyte with a good balance between desirable electrochemical properties, high dielectric constant, and low viscosity. This electrolyte has been shown to have good electrochemical performance even at low temperatures, making it suitable for use in cold environments.

Produit(s) apparenté(s)

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 2 Oral

Organes cibles

Kidney

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

77.0 °F

Point d'éclair (°C)

25 °C


Certificats d'analyse (COA)

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

A Study of the Physical Properties of Li-Ion Battery Electrolytes Containing Esters
Logan, E.R.
Journal of the Electrochemical Society, 165 (2018)
Sodium-ion batteries: present and future
Hwang, Jang-Yeon
Chemical Society Reviews, 12 (2017)
Comparative study on the ionic conductivities and redox properties of LiPF6 and LiTFSI electrolytes and the characteristics of their rechargeable lithium ion batteries
Septiana, A. R.
IOP Conference Series: Materials Science and Engineering, 432 (2018)

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