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Merck

53604

Sigma-Aldrich

Nε-Trifluoroacetyl-L-lysine

≥96.0% (TLC)

Sinónimos:

ε-TFA-lysine

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About This Item

Fórmula empírica (notación de Hill):
C8H13F3N2O3
Número de CAS:
Peso molecular:
242.20
Beilstein/REAXYS Number:
2122429
MDL number:
UNSPSC Code:
12352209
PubChem Substance ID:
NACRES:
NA.26

assay

≥96.0% (TLC)

form

powder

impurities

≤7% water

color

white to off-white

mp

>215 °C

solubility

2 M HCl: 10 mg/mL, clear, colorless

application(s)

peptide synthesis

storage temp.

2-8°C

SMILES string

N[C@@H](CCCCNC(=O)C(F)(F)F)C(O)=O

InChI

1S/C8H13F3N2O3/c9-8(10,11)7(16)13-4-2-1-3-5(12)6(14)15/h5H,1-4,12H2,(H,13,16)(H,14,15)/t5-/m0/s1

InChI key

PZZHRSVBHRVIMI-YFKPBYRVSA-N

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Biochem/physiol Actions

Nε-Trifluoroacetyl-L-lysine is an inhibitor of L-lysine cyclodeaminase.
Nε-Trifluoroacetyl-L-lysine may be used to create synthetic organic polypeptides useful for nonaqueous capillary electrophoresis (NACE).

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Los clientes también vieron

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Hervé Cottet et al.
Analytical chemistry, 75(20), 5554-5560 (2004-01-09)
Poly(Nepsilon-trifluoroacetyl-L-lysine) was used as a model solute to investigate the potential of nonaqueous capillary electrophoresis (NACE) for the characterization of synthetic organic polymers. The information obtained by NACE was compared to that derived from size exclusion chromatography (SEC) experiments, and
Georgia Eleni Tsotsou et al.
Biochimie, 89(5), 591-604 (2007-02-13)
L-Lysine cyclodeaminase from Streptomyces pristinaespiralis was heterologously expressed in Escherichia coli, isolated to 90% purity after two purification steps and characterised. The size of the isolated recombinant enzyme was in agreement with the theoretical size calculated from the corresponding gene.
Gerhard K E Scriba
Journal of chromatography. A, 1159(1-2), 28-41 (2007-02-24)
Nonaqueous background electrolytes broaden the application of capillary electrophoresis displaying altered separation selectivity and interactions between analytes and buffer additives compared to aqueous background electrolytes. In addition, nonaqueous capillary electrophoresis (NACE) appears to be ideally suited for online coupling with
Min He et al.
Gene, 377, 109-118 (2006-06-30)
Meridamycin is a non-immunosuppressive, FKBP12-binding natural macrolide with potential therapeutic applications in a variety of medical conditions. To set the stage for structural modification of meridamycin by genetic engineering, we have cloned and completely sequenced approximately 117 kb of DNA
Determination of synthetic polypeptide conformations and molecular geometrical parameters by nonaqueous CE.
Plasson R, Vayaboury W, Giani O, Cottet H.
Electroanalysis, 28, 3617-3624 (2007)

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