426296

Tetramethylammonium bromide

ACS reagent, ≥98.0%

• Sinónimos: N,N,N-trimethyl-methanaminium bromide, TMAB
• Fórmula lineal: (CH₃)₄N(Br)
• Número de CAS: 64-20-0
• Peso molecular: 154.05
• Beilstein: 3620955
• Número CE: 200-581-2
• Número MDL: MFCD00011626
• Código UNSPSC: 12352100
• ID de la sustancia en PubChem: 24866694
• NACRES: NA.21

Propiedades

• grado: ACS reagent
• Nivel de calidad: 200
• Ensayo: ≥98.0%
• Formulario: powder
• impurezas: ≤0.5% trimethylamine hydrobromide; ≤0.5% trimethylamine
• mp: >300 °C (lit.)
• grupo funcional: amine
• cadena SMILES: [Br-].C[N+](C)(C)C
• InChI: 1S/C4H12N.BrH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
• Clave InChI: DDFYFBUWEBINLX-UHFFFAOYSA-M

Descripción

Descripción general

Tetrabutylammonium bromide is a quaternary ammonium compound that is widely used as a phase transfer catalyst. Absolute viscosities of its aqueous solutions have been measured at various temperatures (20,25 and 30°C). Various physical properties (activity coefficient up to saturation, conductance, density and solubility in water) of TMABr have been evaluated.

Aplicación

Tetrabutylammonium bromide (TBAB) may be used in the molten state in the following processes:

• Synthesis of (2S)-5-(3-phenyl-2-phthalimidylpropanoylamino)isophthalic acid.
• Synthesis of alkyl-substituted pyrroles in the absence of catalyst and organic solvent.
• Synthesis of dithioacetals from acetals by transthioacetalisation in a solvent free environment.
• Synthesis of polyamides (PAs) by the polymerization of terephthalic acid and diisocyanates.
• Catalyze the addition of thiols to conjugated alkenes.
• Dehydrochlorination of poly(vinyl chloride).

Información de seguridad

• Pictogramas: GHS06
• Palabra de señalización: Danger
• Frases de peligro: H300
• Consejos de prudencia: P301 + P330 + P331 + P310
• Clasificaciones de peligro: Acute Tox. 2 Oral
• Código de clase de almacenamiento: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable
• Equipo de protección personal: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges