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Merck

933961

Sigma-Aldrich

1,1,2,2-Tetrafluoroethyl 2,2,3,3-tetrafluoropropylether

greener alternative

≥99%, <=10 ppm acid, battery grade

Sinónimos:

1,1,2,2-Tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane, HFE-458, TTE

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About This Item

Fórmula empírica (notación de Hill):
C5H4F8O
Número de CAS:
Peso molecular:
232.07
Número MDL:
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
NACRES:
NA.21

grado

battery grade

Nivel de calidad

descripción

Application: Battery manufacturing

Ensayo

≥99%

Formulario

liquid

características de los productos alternativos más sostenibles

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sustainability

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impurezas

≤10 ppm Acid
≤100 ppm Non-volatile residue
≤750 ppm H2O

bp

92 °C

densidad

1.54 g/mL

aplicaciones

battery manufacturing

categoría alternativa más sostenible

cadena SMILES

FC(F)(OCC(F)(F)C(F)F)C(F)F

InChI

1S/C5H4F8O/c6-2(7)4(10,11)1-14-5(12,13)3(8)9/h2-3H,1H2

Clave InChI

HCBRSIIGBBDDCD-UHFFFAOYSA-N

Descripción general

Our 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropylether (TTE) is a high-purity, battery-grade fluorinated ether commonly used as an electrolyte solvent in lithium-ion batteries (LIBs). It is a clear liquid with a boiling point of 92 °C that is miscible with many polar organic solvents, including carbonates typically used in battery electrolytes. Our TTE is produced to meet the high standards of battery-grade purity, ensuring a minimum purity level of 99%, and is carefully purified to become anhydrous and acid-free, making it a reliable choice for battery applications.
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Aplicación

1,1,2,2-Tetrafluoroethyl 2,2,3,3-tetrafluoropropylether (TTE) is a highly versatile fluorinated ether that finds its use as a co-solvent and additive in a range of battery systems, including lithium-sulfur batteries (LSBs) and lithium-ion batteries (LiBs). In LSBs, TTE plays a crucial role in reducing the solubility of intermediate lithium polysulfides, thereby preventing the polysulfide shuttle (PSS) effect and improving battery performance. Recent research suggests that TTE can also lead to the formation of a compact and uniform surface layer on the lithium anode when used as an additive, which improves the efficiency and stability of Li-S batteries. In LiBs, TTE acts as a cosolvent, reducing the viscosity of the electrolyte and enabling the use of lower concentrations of lithium salt without compromising ionic conductivity. Additionally, TTE has been shown to help form a stable, conductive solid electrolyte interphase (SEI) on both graphite anodes and NMC cathodes, thereby improving the overall electrochemical performance of the battery.

Pictogramas

Flame

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Flam. Liq. 3

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

80.6 °F - closed cup

Punto de inflamabilidad (°C)

27 °C - closed cup


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Visite la Librería de documentos

Fluoro-Ether as a Bifunctional Interphase Electrolyte Additive with Graphite/LiNi0.5Co0.2Mn0.3O2 Full Cell
[3]Heng, et al.
ACS Applied Energy Materials, 2, 6404-6416 (2019)
Partially Fluorinated Ether as an Electrolyte Additive to Modify Electrode Surface and Suppress Dissolution of Polysulfides in Li-S Batteries
Qian, Feng
Electrochemical Energy Technology , 4 (2018)
Synthesis and electrochemical properties of partially fluorinated ether solvents for lithiumsingle bondsulfur battery electrolytes
Yue Zheng, et al.
Journal of Power Sources, 401, 271-277 (2018)

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