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Merck

267112

Sigma-Aldrich

Palladium

wire, diam. 1.0 mm, 99.9% trace metals basis

Sinónimos:

Palladium (powder), Palladium black, Palladium element

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About This Item

Fórmula lineal:
Pd
Número de CAS:
Peso molecular:
106.42
EC Number:
MDL number:
UNSPSC Code:
12141733
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.9% trace metals basis

form

wire

resistivity

9.96 μΩ-cm, 20°C

diam.

1.0 mm

bp

2970 °C (lit.)

mp

1554 °C (lit.)

density

12.02 g/cm3 (lit.)

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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Application

Palladium is widely used as a metal wire electrode to synthesize Pd-based nanomaterials with good electrocatalytic activity. For example, it is used to prepare carbon-supported Pd nanoclusters and PdAu nanoparticles.

Itcan also be used as a hydrogenation catalyst in various organic reactions, suchas hydrogenation of alkenes and alkynes to their corresponding hydrocarbons.

Quantity

900 mg = 10 cm; 9 g = 100 cm

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Bin Kim et al.
Journal of nanoscience and nanotechnology, 13(1), 517-522 (2013-05-08)
In order to form flexible printed circuits through inkjet printing technique, the Pd(ll) catalyst ink was printed on the surface of polyimide film modified with KOH solution and then reduced with NaBH4 solution to extract the Pd(O) catalyst nuclei. The
Stefano Nicolai et al.
The Journal of organic chemistry, 78(8), 3783-3801 (2013-03-21)
Tetrahydrofurans and pyrrolidines are among the most important heterocycles found in bioactive compounds. Cyclization-functionalization domino reactions of alcohols or amines onto olefins constitute one of the most efficient methods to access them. In this context, oxy- and aminoalkynylation are especially
Xuxing Chen et al.
Organic & biomolecular chemistry, 11(16), 2582-2585 (2013-03-19)
A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.
Meifang Zheng et al.
Organic letters, 15(8), 1838-1841 (2013-04-02)
Palladium-catalyzed oxidative difunctionalization of enol ethers with 1,3-dicarbonyl compounds to construct trisubstituted furans in one step under mild conditions is described. The reaction is thought to proceed through a C-C bond formation along with a C-O bond closing the ring
Meng Wang et al.
Organic & biomolecular chemistry, 11(16), 2574-2577 (2013-03-15)
A novel Pd/Cu catalyzed domino reaction for the synthesis of functionalized pyrrolo[1,2-b]pyridazines from readily accessible (hetero)aryl propargyl alcohols and 1-amino-2-bromopyrroles was developed. This cascade process involves a Sonogashira cross-coupling reaction, an isomerization and an intramolecular condensation.

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