33233

Esametilentetrammina

≥99.5% (calc. to the dried substance), solid, puriss. p.a., reag. Ph. Eur.

• Sinonimo/i: 1,3,5,7-tetraazatriciclo[3.3.1.1^3,7]decano, Esamina, Metenamina, Urotropina
• Formula empirica (notazione di Hill): C₆H₁₂N₄
• Numero CAS: 100-97-0
• Peso molecolare: 140.19
• NACRES: NA.21
• PubChem Substance ID: 57648782
• UNSPSC Code: 12352100
• EC Number: 202-905-8
• MDL number: MFCD00006895
• Beilstein/REAXYS Number: 2018
• Assay: ≥99.5% (calc. to the dried substance)
• Form: solid

Proprietà

• Nome del prodotto: Esametilentetrammina, puriss. p.a., reag. Ph. Eur., ≥99.5% (calc. to the dried substance)
• Quality Segment: 100
• agency: USP/NF, reag. Ph. Eur.
• vapor pressure: <0.01 mmHg ( 20 °C)
• grade: puriss. p.a.
• assay: ≥99.5% (calc. to the dried substance)
• form: solid
• autoignition temp.: 770 °F
• impurities: ≤0.001% heavy metals (as Pb), ≤0.01% ammonium (NH₄)
• ign. residue: ≤0.01% (as SO₄)
• pH: 8.5-9.5 (20 °C, 10%)
• mp: 280 °C (subl.) (lit.)
• solubility: H₂O: soluble
• anion traces: chloride (Cl^-): ≤20 mg/kg, sulfate (SO₄^2-): ≤50 mg/kg
• SMILES string: C1N2CN3CN1CN(C2)C3
• InChI: 1S/C6H12N4/c1-7-2-9-4-8(1)5-10(3-7)6-9/h1-6H2
• InChI key: VKYKSIONXSXAKP-UHFFFAOYSA-N

Descrizione

General description

Hexamethylenetetramine is a hexamine. It participates in Duff reaction for the synthesis of o-hydroxybenzaldehyde derivatives.

Application

Hexamethylenetetramine may be used as reagent in the synthesis of 3 and 5-aldehydo salicylic acid, and 2-hydroxy naphthaldehyde, via reaction with salicylic acid and β-naphthol respectively, followed by the treatment with HCl (hydrolysis). It may be used for the synthesis of phenolic aldehydes. It may be used as formylating reagent for the synthesis of various aldehydes.
It has been used for the preparation of ceria nanoparticles, via precipitation method.

Informazioni sulla sicurezza

• pictograms: GHS02,GHS07
• signalword: Warning
• hcodes: H228,H317
• pcodes: P210 - P240 - P241 - P261 - P280 - P302 + P352
• Hazard Classifications: Flam. Sol. 2 - Skin Sens. 1B
• Classe di stoccaggio: 4.1B - Flammable solid hazardous materials
• flash_point_f: 482.0 °F - closed cup
• flash_point_c: 250 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges