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00070

Sigma-Aldrich

Acetaldeide

puriss. p.a., anhydrous, ≥99.5% (GC)

Sinonimo/i:

Etanale

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About This Item

Formula condensata:
CH3CHO
Numero CAS:
Peso molecolare:
44.05
Beilstein:
505984
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
eCl@ss:
39021102
ID PubChem:
NACRES:
NA.21

Origine biologica

synthetic

Livello qualitativo

Grado

anhydrous
puriss. p.a.

Densità del vapore

1.52 (vs air)

Tensione di vapore

14.63 psi ( 20 °C)

Saggio

≥99.5% (GC)

Forma fisica

liquid

Temp. autoaccensione

365 °F

Qualità

anhydrous

Limite di esplosione

60 %

Impurezze

≤0.5% free acid (as CH3COOH)

Residuo dopo evaporazione

≤0.002%

Indice di rifrazione

n20/D 1.332 (lit.)
n20/D 1.332

P. eboll.

21 °C (lit.)

Punto di fusione

−125 °C (lit.)

Densità

0.785 g/mL at 25 °C (lit.)

Cationi in tracce

Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.5 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

Temperatura di conservazione

2-8°C

Stringa SMILE

CC=O

InChI

1S/C2H4O/c1-2-3/h2H,1H3
IKHGUXGNUITLKF-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Acetaldehyde is an organic colorless flammable liquid. It can be produced by hydration of acetylene and by catalytic oxidation of ethyl alcohol. It is mainly used in manufacturing acetic acid.
Mechanism of the thermal decomposition of acetaldehyde has been reported. It is a product of ethanol metabolism in the liver, binds covalently to various proteins, thereby alters the liver function and structure. The aldol condensation of acetaldehyde and heptanal in the presence of hydrotalcite-type catalysts has been described.

Applicazioni

Acetaldehyde may be used for the enzymatic synthesis of fatty acids.
It was used in the plasma polymerization for deposition of reactive aldehyde groups onto substrate, in a study to produce fibrous biomaterials with cell adhesive and also repulsive capability in biomedical applications. It was also used as calibration standard during determination of acetone, acetaldehyde, ethanol, and methanol in different human matrices, such as whole blood, vitreous humour, and urine using gas chromatography with flame ionization detection method (GC–FID).

Avvertenza

forms easily paraldehyde

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 1 - Muta. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

-38.0 °F - closed cup

Punto d’infiammabilità (°C)

-38.89 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves


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Raghu Sivaramakrishnan et al.
The journal of physical chemistry. A, 119(28), 7724-7733 (2015-03-21)
The mechanism for the thermal decomposition of acetaldehyde has been revisited with an analysis of literature kinetics experiments using theoretical kinetics. The present modeling study was motivated by recent observations, with very sensitive diagnostics, of some unexpected products in high
Acetaldehyde plasma polymer-coated PET fibers for endothelial cell patterning: Chemical, topographical, and biological analysis.
Hadjizadeh, Afra.
Journal of Biomedical Materials Research. Part B, Applied Biomaterials, 94.1, 11-21 (2010)
The aldol condensation of acetaldehyde and heptanal on hydrotalcite-type catalysts.
Tichit D, et al.
J. Catal., 219(1), 167-175 (2003)
GC determination of acetone, acetaldehyde, ethanol, and methanol in biological matrices and cell culture.
Pontes, Helena, et al.
Journal of Chromatographic Science, 47.4, 272-278 (2009)
C S Lieber
Biochemical Society transactions, 16(3), 241-247 (1988-06-01)
Acetaldehyde, the toxic product of ethanol metabolism in the liver, covalently binds to a variety of proteins, thereby altering liver function and structure. Through its binding to tubulin, acetaldehyde decreases the polymerization of microtubules thereby impairing protein secretion and favouring

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