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C39601

Sigma-Aldrich

Chlorodiphenylphosphine

96%

Sinonimo/i:

P-Chlorodiphenylphosphine, ClPPh2, PPh2Cl, Diphenylphosphinous chloride

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About This Item

Formula condensata:
(C6H5)2PCl
Numero CAS:
Peso molecolare:
220.63
Beilstein:
512032
Numero CE:
Numero MDL:
Codice UNSPSC:
12352128
ID PubChem:
NACRES:
NA.22
Prezzi e disponibilità al momento non sono disponibili

Densità del vapore

7.8 (vs air)

Livello qualitativo

Saggio

96%

Stato

liquid

Impiego in reazioni chimiche

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

Indice di rifrazione

n20/D 1.636 (lit.)

P. ebollizione

320 °C (lit.)

Densità

1.194 g/mL at 25 °C
1.229 g/mL at 25 °C (lit.)

Gruppo funzionale

phosphine

Stringa SMILE

ClP(c1ccccc1)c2ccccc2

InChI

1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
XGRJZXREYAXTGV-UHFFFAOYSA-N

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Descrizione generale

Ph2PCl is an efficient reagent for cross-coupling reactions and for introducing the Ph2P group into molecules.[1]

Applicazioni

Precursors used in the synthesis of various phosphines.
Used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation.[2][3]

Pittogrammi

CorrosionExclamation mark

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Rischi supp

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

280.4 °F

Punto d’infiammabilità (°C)

138 °C

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Certificati d'analisi (COA)

Lot/Batch Number

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I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

Visita l’Archivio dei documenti

Chemical & Pharmaceutical Bulletin, 41, 1149-1149 (1993)
Journal of the Chemical Society. Perkin Transactions 1, 1433-1433 (1993)
Synthesis, 3631-3631 (2006)
Synlett, 3150-3150 (2006)
Resorcinarenyl-Phosphines in Suzuki--Miyaura Cross-Coupling Reactions of Aryl Chlorides
Monnereau L, et al.
European Journal of Inorganic Chemistry, 2014, 1364-1372 (2014)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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