710210

(E)-3-(tert-Butyldimethylsilyloxy)propene-1-yl-boronic acid pinacol ester

97%

• Sinonimo/i: (E)-2-[3-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]-1-propenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-[(1E)-3-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]-1-propenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, tert-Butyldimethyl[[(2E)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)prop-2-en-1-yl]oxy]silane
• Formula empirica (notazione di Hill): C₁₅H₃₁BO₃Si
• Numero CAS: 114653-19-9
• Peso molecolare: 298.30
• Numero MDL: MFCD15144803
• Codice UNSPSC: 12352103
• ID PubChem: 329762909
• NACRES: NA.22

Proprietà

• Saggio: 97%
• Stato: liquid
• Densità: 0.910 g/mL at 25 °C
• Stringa SMILE: CC(C)(C)[Si](C)(C)OC\C=C\B1OC(C)(C)C(C)(C)O1
• InChI: 1S/C15H31BO3Si/c1-13(2,3)20(8,9)17-12-10-11-16-18-14(4,5)15(6,7)19-16/h10-11H,12H2,1-9H3/b11-10+; LUURLZJMKOVITO-ZHACJKMWSA-N

Descrizione

Applicazioni

(E)-3-(tert-Butyldimethylsilyloxy)propene-1-yl-boronic acid pinacol ester can be used as a reactant in:

• Palladium-catalyzed Suzuki-Miyaura coupling reaction.[1]
• The synthesis of anti-homoallylic alcohols by allylation reaction with aldehydes in the presence of iridium complex-catalyst.[2]
• The preparation of α-imino aldehydes.[3]

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 10 - Combustible liquids
• Classe di pericolosità dell'acqua (WGK): WGK 2
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable