559148

Ethyl (2-methylbenzoyl)acetate

97%

• Sinonimo/i: Ethyl 2-(2-methylbenzoyl)acetate, Ethyl 3-(2-methylphenyl)-3-oxopropanoate, Ethyl 3-oxo-3-(o-tolyl)propanoate, Ethyl o-methylbenzoylacetate, Ethyl o-toluoylacetate
• Formula condensata: CH₃C₆H₄COCH₂CO₂CH₂CH₃
• Numero CAS: 51725-82-7
• Peso molecolare: 206.24
• Numero MDL: MFCD03424817
• Codice UNSPSC: 12352100
• ID PubChem: 24879799
• NACRES: NA.22

Proprietà

• Saggio: 97%
• Indice di rifrazione: n20/D 1.5255 (lit.)
• P. ebollizione: 256-257 °C (lit.)
• Densità: 1.069 g/mL at 25 °C (lit.)
• Stringa SMILE: CCOC(=O)CC(=O)c1ccccc1C
• InChI: 1S/C12H14O3/c1-3-15-12(14)8-11(13)10-7-5-4-6-9(10)2/h4-7H,3,8H2,1-2H3; UNULPFKXRJPSCO-UHFFFAOYSA-N

Descrizione

Descrizione generale

Ethyl (2-methylbenzoyl)acetate is a β-keto ester. It undergoes Co/Mn mediated oxidative coupling reaction with various indole derivatives.

Applicazioni

Reactant for:

• Preparation of highly substituted furans by tandem condensation-cyclization reactions using bismuth triflate catalyst
• Co/Mn-mediated oxidative cross-coupling
• Enantioselective ruthenium-catalyzed hydrogenation
• Preparation of cambinol analogs for sirtuin inhibition with antitumor action

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 12 - Non Combustible Liquids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: Eyeshields, Gloves