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208523

Sigma-Aldrich

Ruthenium(III) chloride

Ru content 45-55%

Sinonimo/i:

Ruthenium trichloride

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About This Item

Formula condensata:
RuCl3
Numero CAS:
10049-08-8
Peso molecolare:
207.43
Numero CE:
233-167-5
Numero MDL:
MFCD00011208
Codice UNSPSC:
12161600
ID PubChem:
24852520
NACRES:
NA.22

Forma fisica

solid

Impiego in reazioni chimiche

core: ruthenium
reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

Densità

3.11 g/mL at 25 °C (lit.)

Stringa SMILE

Cl[Ru](Cl)Cl

InChI

1S/3ClH.Ru/h3*1H;/q;;;+3/p-3
YBCAZPLXEGKKFM-UHFFFAOYSA-K

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Categorie correlate

Descrizione generale

Ruthenium(III) chloride is a chemical compound, that can be used as a mild Lewis acid catalyst for the acetalization of aldehydes, acetalization of alcohols, and conversion of ketoximes to amides. Additionally, it can also be used as a precursor to synthesize Ru nanoparticles.

Applicazioni

Ruthenium(III) chloride is used as a catalyst:

  • In the synthesis of β‐amino alcohols by nucleophilic opening of epoxides with anilines.
  • In the acetylation of varies of phenols, alcohols, thiols, and amines under mild conditions.
  • In the synthesis of α‐aminonitriles by mixing aldehydes, amines, and trimethylsilyl cyanides.

Altre note

insoluble form

Avvertenze

Danger

Indicazioni di pericolo

H302,H314,H411

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

8B - Non-combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificati d'analisi (COA)

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RuCl3 Catalyzed One-Pot Synthesis of ?-Aminonitriles
De SK
Synthetic Communications, 35(5), 653-656 (2005)
Mohamed Fouad et al.
Journal of hazardous materials, 402, 123514-123514 (2020-07-28)
We selected ruthenium (Ru) to improve the photocatalytic activity of a WO3/ZrO2 composite. The synthesized Ru/WO3/ZrO2 was then compared to a benchmark photocatalyst (S-TiO2) in terms of photocatalytic disinfection of raw surface waters collected from the Nile Delta region, Egypt.
Shū Kobayashi et al.
Organic letters, 4(8), 1319-1322 (2002-04-13)
Several transition metal salts were found to catalyze aza-Michael reactions of enones with carbamates efficiently. The catalytic activity was strongly dependent on the nature of the metal salts. While conventional Lewis acids such as BF(3).OEt(2), AlCl(3), or TiCl(4) showed lower
Hitoshi Harada et al.
The Journal of organic chemistry, 73(17), 6772-6779 (2008-08-07)
Highly enantioselective catalytic intramolecular ortho-alkylation of aromatic imines containing alkenyl groups tethered at the meta position relative to the imine directing group has been achieved using [RhCl(coe)2]2 and chiral phosphoramidite ligands. Cyclization of substrates containing 1,1- and 1,2-disubstituted as well
Halloysite nanotube supported Ru nanocatalysts synthesized by the inclusion of preformed Ru nanoparticles for preferential oxidation of CO in H2-rich atmosphere
Wang L, et al
The Journal of Physical Chemistry C, 117(8), 4141-4151 (2013)
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