194654
Chrysanthemyl alcohol, mixture of cis and trans
98%
Sinonimo/i:
2,2-Dimethyl-3-(2-methylpropenyl)cyclopropanemethanol, Chrysanthemol
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About This Item
Formula condensata:
(CH3)2C3H2[CH=C(CH3)2]CH2OH
Numero CAS:
Peso molecolare:
154.25
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
Prodotti consigliati
Saggio
98%
Indice di rifrazione
n20/D 1.475 (lit.)
P. ebollizione
66-69 °C/0.07 mmHg (lit.)
Densità
0.888 g/mL at 25 °C (lit.)
Stringa SMILE
C\C(C)=C\C1C(CO)C1(C)C
InChI
1S/C10H18O/c1-7(2)5-8-9(6-11)10(8,3)4/h5,8-9,11H,6H2,1-4H3
HIPIENNKVJCMAP-UHFFFAOYSA-N
Descrizione generale
Oxidation of chrysanthemyl alcohol in the presence of [RuO4]2- yields chrysantheniic acid.
Applicazioni
Chrysanthemyl alcohol was used in the determination of position of double bonds in various terepenes and branched chain compounds.
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Oxo complexes of ruthenium (VI) and (VII) as organic oxidants.
Green G, et al.
Journal of the Chemical Society. Perkin Transactions 1, 681-686 (1984)
A B Attygalle et al.
Analytical chemistry, 65(18), 2528-2533 (1993-09-15)
The electron-impact mass spectra of alpha, beta-bis(methylthio) derivatives of certain terpenes and other compounds with branched alkenyl groups contain diagnostic peaks that can be used for locating the position of the double bond in the parent compound. In contrast to
[Studies on the chemical constituents of Chrysanthemum indicum L].
D Q Yu et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 22(11), 837-840 (1987-11-01)
L Y Mou et al.
Journal of Asian natural products research, 3(2), 103-116 (2001-06-16)
Chrysanthemol (1), a trans-eudesmane type sesquiterpene from Chrysanthemum indicum L., possesses certain anti-inflammatory activity. Its total synthesis was approached from two alternative routes and finally accomplished in ten steps from R-(+)-carvone via alpha-eudesmol (10) as the key intermediate. The overall
Gas chromatographic determination of racemic cis- and trans-chrysanthemols and their potential aldehyde and carboxylic acid microbial metabolites.
M Miski et al.
Journal of chromatography, 437(2), 436-441 (1988-03-25)
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