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186317

Sigma-Aldrich

N,N-Diethylformamide

99%

Sinonimo/i:

N-Formyldiethylamine

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About This Item

Formula condensata:
HCON(C2H5)2
Numero CAS:
617-84-5
Peso molecolare:
101.15
Beilstein:
1209392
Numero CE:
210-533-2
Numero MDL:
MFCD00003287
Codice UNSPSC:
12352100
ID PubChem:
24851213
NACRES:
NA.22

Saggio

99%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.434 (lit.)

P. eboll.

176-177 °C (lit.)

Densità

0.908 g/mL at 25 °C (lit.)

Stringa SMILE

CCN(CC)C=O

InChI

1S/C5H11NO/c1-3-6(4-2)5-7/h5H,3-4H2,1-2H3
SUAKHGWARZSWIH-UHFFFAOYSA-N

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Descrizione generale

N,N-Diethylformamide undergoes condensation with aromatic o-aminonitriles in the presence of ZnCl2 in sealed reactor to yield quinazoline-2,4(1H,3H)-dione.

Applicazioni

N,N-Diethylformamide was used in the synthesis of metal-organic frameworks. It was also used as solvent in the synthesis of porous cubic-shaped ZnO particles.

Pittogrammi

FlameExclamation mark
GHS02,GHS07

Avvertenze

Warning

Indicazioni di pericolo

H226,H315,H319,H335

Classi di pericolo

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Classe di pericolosità dell'acqua (WGK)

WGK 1

Dispositivi di protezione individuale

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

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Yingmu Zhang et al.
Dalton transactions (Cambridge, England : 2003), 47(34), 11806-11811 (2018-06-05)
A new luminescent mesoporous metal-organic framework (PCN-604) was successfully synthesized from trimetric clusters, Al3(O)(CH3COO)6, and pyridine-based tritopic linkers, 4,4',4''-(pyridine-2,4,6-triyl)tribenzoate (PTB), via a solvothermal reaction. The MOF with an MTN topology possesses remarkable aqueous and thermal stabilities. Due to the efficient
Yuxia Shen et al.
Advanced materials (Deerfield Beach, Fla.), 30(52), e1802497-e1802497 (2018-11-06)
Large-scale synthesis of van der Waals (vdW) metal-organic framework (MOF) nanosheets with controlled crystallinity and interlayer coupling strength is one of the bottlenecks in 2D materials that has limited its successful transition to large-scale applications. Here, scalable synthesis of mBDC
Yu Kimitsuka et al.
Inorganic chemistry, 52(24), 14028-14033 (2013-11-26)
A method for synthesizing porous cubic-shaped ZnO particles a few tens of micrometers in size is described on the basis of a pyrolytic conversion of Zn-terephthalate metal-organic frameworks (MOFs). MOF crystals were initially grown in solutions containing Zn(NO3)2·6H2O and terephthalic
G Amato et al.
Toxicology letters, 124(1-3), 11-19 (2001-10-31)
N-N, dimethyl- (DMF) and N-N, diethyl-formamide (DEF) are two hepatotoxic solvents, whose metabolism has not been investigated in humans. To identify the P450 isoforms involved in the microsomal oxidation of these solvents we used (a) 12 human liver samples; (b)
Renzo Arias-Ugarte et al.
Journal of the American Chemical Society, 134(2), 848-851 (2012-01-17)
We demonstrate that using Mo(CO)(6), Mo(CO)(5)NMe(3), and (η(5)-C(5)H(5))Mn(CO)(3) as catalysts for the silane, R(3)SiH, reduction of N,N-dimethylformamide (DMF), and N,N-diethylformamide (DEF), we can observe, intercept, and isolate, the important siloxymethylamine intermediates, R(3)SiOCH(2)NR'(2), R' = Me, Et, for the first time.
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