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Documenti

156876

Sigma-Aldrich

N-(2-Hydroxyethyl)aniline

98%

Sinonimo/i:

2-(Phenylamino)ethanol, 2-Anilinoethanol, N-Phenylethanolamine

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About This Item

Formula condensata:
C6H5NHCH2CH2OH
Numero CAS:
122-98-5
Peso molecolare:
137.18
Beilstein:
774672
Numero MDL:
MFCD00002832
Codice UNSPSC:
12352100
ID PubChem:
24849642
NACRES:
NA.22

Densità del vapore

>1 (vs air)

Tensione di vapore

<0.01 mmHg ( 20 °C)

Saggio

98%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.578 (lit.)

P. eboll.

278-282 °C/760 mmHg (lit.)

Densità

1.094 g/mL at 25 °C (lit.)

Stringa SMILE

OCCNc1ccccc1

InChI

1S/C8H11NO/c10-7-6-9-8-4-2-1-3-5-8/h1-5,9-10H,6-7H2
MWGATWIBSKHFMR-UHFFFAOYSA-N

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Applicazioni

N-(2-Hydroxyethyl)aniline was employed as substrate for human olfactory UDP-glucuronosyltransferase.

Avvertenze

Danger

Indicazioni di pericolo

H301,H310,H318,H370,H373,H411

Classi di pericolo

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 - STOT SE 1

Organi bersaglio

Blood, Blood,hematopoietic system

Codice della classe di stoccaggio

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

235.4 °F - closed cup

Punto d’infiammabilità (°C)

113 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificati d'analisi (COA)

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Mercedes Amat et al.
Natural product communications, 6(4), 515-526 (2011-05-13)
This review is focused on recent synthetic achievements and ongoing work in our laboratory using phenylglycinol-derived oxazolopiperidone lactams as starting materials for the enantioselective synthesis of piperidine-containing alkaloids: madangamines, 2,5-disubstituted decahydroquinoline and 1-substituted tetrahydroisoquinoline alkaloids, the indole alkaloids 20S- and
Mercedes Amat et al.
Organic & biomolecular chemistry, 9(7), 2175-2184 (2011-02-08)
The double cyclocondensation of symmetric pyridyl bis(oxoacids) 2b and 3b with (R)-phenylglycinol stereoselectively gave access to bis-phenylglycinol-derived oxazolopyrrolidine 9 and oxazolopiperidone 10, respectively. Application of the stereocontrolled cyclocondensation reaction to phenyl bis-γ-oxoacid 4b provided 11, which was converted to the
M Amat et al.
Organic letters, 3(21), 3257-3260 (2001-10-12)
[reaction: see text]. The phenylglycinol-derived 2-pyridone 1 undergoes m-CPBA oxidation steroselectively leading to the chiral nonracemic unsaturated bicyclic hydroxylactam 2, from which the enantioselective synthesis of (3R,5R)-3,4,5-trihydroxypiperidine (16) and the formal synthesis of the azasugar epiisofagomine are described. The enantioselective
Mercedes Amat et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(28), 7724-7732 (2011-06-15)
Phenylglycinol-derived, unsaturated oxazolopiperidone lactams are extremely useful building blocks that undergo stereoselective conjugate addition reactions with organocuprates, enolates, and sulfur-stabilized anions, allowing the stereocontrolled introduction of substituents at the piperidine 4-position. The factors governing the exo- or endo-facial selectivity are
Santos Fustero et al.
The Journal of organic chemistry, 74(11), 4429-4432 (2009-05-15)
The preparation of cyclic dipeptide mimetics from chiral imino lactones derived from (R)-phenylglycinol is described. Key steps of the synthetic route included the fully stereoselective construction of a quaternary center, the formation of six-, seven-, or eight-membered lactams by means
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