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650536

Sigma-Aldrich

Heptane

greener alternative

HPLC Plus, for HPLC, GC, and residue analysis, 99%

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About This Item

Formule linéaire :
CH3(CH2)5CH3
Numéro CAS:
Poids moléculaire :
100.20
Beilstein:
1730763
Numéro CE :
Numéro MDL:
Code UNSPSC :
12190000
ID de substance PubChem :
Nomenclature NACRES :
NA.06
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Qualité

HPLC Plus

Niveau de qualité

Densité de vapeur

3.5 (vs air)

Pression de vapeur

40 mmHg ( 20 °C)
83 mmHg ( 37.7 °C)

Essai

≥98.5% (GC)
99%

Forme

liquid

Température d'inflammation spontanée

433 °F

Limite d'explosivité

7 %

Caractéristiques du produit alternatif plus écologique

Safer Solvents and Auxiliaries
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Impuretés

≤0.0001% non-volatiles
≤0.01% water (Karl Fischer)
≤1.0 ppb Fluorescence (quinine) at 365 nm

Résidus halogénés

≤2 μg/L (as heptachlor epoxide)

Indice de réfraction

n20/D 1.3850-1.3890
n20/D 1.387 (lit.)

pb

98 °C (lit.)

Pf

−91 °C (lit.)

Solubilité

acetone: miscible(lit.)
carbon tetrachloride: soluble(lit.)
ethanol: very soluble(lit.)
water: insoluble(lit.)

Densité

0.684 g/mL at 25 °C (lit.)

λ

H2O reference

Absorption UV

λ: 200 nm Amax: ≤1.0
λ: 225 nm Amax: ≤0.10
λ: 250 nm Amax: ≤0.01
λ: 300-400 nm Amax: ≤0.005

Adéquation

corresponds for IR spectroscopy
suitable for residue analysis

Application(s)

food and beverages

Autre catégorie plus écologique

Chaîne SMILES 

CCCCCCC

InChI

1S/C7H16/c1-3-5-7-6-4-2/h3-7H2,1-2H3

Clé InChI

IMNFDUFMRHMDMM-UHFFFAOYSA-N

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Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. Heptane is an environmentally preferable solvent and greener alternative to hexane for HPLC and GC and thus has been enhanced for "Safer Solvents and Auxiliaries". Click here for more information.

Heptane (n-Heptane) is a primary reference fuel (PRF) for the rating of octane numbers of fuels in internal combustion engines. Its cetane number has been reported to be 56. Mechanism and kinetic studies of its oxidation in flow reactors, shock tubes and rapid compression machines have been proposed.[1] Its thermal decomposition has been studied under different conditions of temperature and pressure.[2] Its oxidative dehydrogenation in the presence of magnesium oxide supported vanadium catalyst has been investigated.[3] Molybdenum phosphide supported on Hβ zeolite (MoP/Hβ) catalyzed hydroisomerization of n-heptane has been reported to be enhanced by doping with secondary metals (Cr, Ni or Ce).[4]

Application

Greener alternatives to Hexane in HPLC.
Spectrophotometry.
Environmental testing.
Heptane (n-Heptane) may be used:
  • To compose the solvent mixtures for the purification of N-acylpyrrolidine derivatives of fatty acid methyl esters (FAMEs) by TLC (Thin Layer Chromatography).[5]
  • To generate chiral alcohols and heptanones, via whole cell double oxidation.[6]
  • As a solvent in the synthesis of isopropyl acetate, via esterification of acetic acid with isopropyl alcohol catalyzed by lipase immobilized on silica.[7]

Caractéristiques et avantages

Greener alternative for hexane

Conditionnement

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
See all the new features here!

Autres remarques

Pesticide Residue Analysis (as Heptachlor Epoxide) <2 μg/L
Pure-Pac® II containers require the Micromatic MacroValve coupler for dispensing solvents, Z560723.

Produits recommandés

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

Informations légales

Pure-Pac is a registered trademark of Merck KGaA, Darmstadt, Germany

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Central nervous system

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

24.8 °F - closed cup

Point d'éclair (°C)

-4 °C - closed cup


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Heptane

High pressure pyrolysis of n-heptane.
Chakraborty JP and Kunzru D.
Journal of Analytical and Applied Pyrolysis, 86(1), 44-52 (2009)
Hydroisomerization of n-heptane over MoP/Hβ catalyst doped with metal additive.
Liu P, et al.
Fuel Processing Technology, 131, 311-316 (2015)
Activation of n-Heptane: A Study with VMgO Catalysts.
Dasireddy VDBC, et al.
Catalysis Letters, 144(4), 590-597 (2014)
Whole-cell double oxidation of n-heptane.
Muller CA, et al.
Journal of Biotechnology, 191, 196-204 (2014)
Madan Lal Verma et al.
Enzyme research, 2011, 919386-919386 (2011-05-24)
Selective production of fragrance fatty acid ester from isopropanol and acetic acid has been achieved using silica-immobilized lipase of Bacillus cereus MTCC 8372. A purified thermoalkalophilic extracellular lipase was immobilized by adsorption onto the silica. The effects of various parameters

Articles

Development and validation of a fatty acid methyl esterification method, using methanolic HCl reagent, for FAME analysis by GC of vegetable oils and fats.

Contenu apparenté

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Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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