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Sigma-Aldrich

Mercury(II) acetate

ACS reagent, ≥98.0%

Synonyme(s) :

Mercuric acetate

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5 G
64.10 CHF
100 G
110.00 CHF
500 G
437.00 CHF

64.10 CHF


Date d'expédition estimée le02 juin 2025


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5 G
64.10 CHF
100 G
110.00 CHF
500 G
437.00 CHF

About This Item

Formule linéaire :
(CH3COO)2Hg
Numéro CAS:
Poids moléculaire :
318.68
Beilstein:
3563831
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352103
ID de substance PubChem :
Nomenclature NACRES :
NB.24

64.10 CHF


Date d'expédition estimée le02 juin 2025


Devis pour commande en gros

Qualité

ACS reagent

Essai

≥98.0%

Forme

powder

Pertinence de la réaction

reagent type: catalyst
core: mercury

Impuretés

≤0.01% insolubles

Résidus de réduction

≤0.02%

Pf

179-182 °C (lit.)

Traces d'anions

chloride (Cl-): ≤0.005%
nitrate (NO3-): ≤0.005%
sulfate (SO42-): ≤0.005%

Traces de cations

Fe: ≤0.001%
Hg+: ≤0.4%
other heavy metals (as Pb): ≤0.002%

Chaîne SMILES 

CC(=O)O[Hg]OC(C)=O

InChI

1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

Clé InChI

BRMYZIKAHFEUFJ-UHFFFAOYSA-L

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Description générale

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed.[1] It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.[2]
Mercury(II) acetate is a reagent mainly used in oxymercuration-demercuration reaction.[3]

Application

Due to its strong affinity towards sulfur, it finds application as a reagent in desulfurization reactions.[3] Mercury(II) acetate may be used in the preparation of mercury(II) acetate-Nafion modified electrode, which can be used in anodic stripping voltammetry for the analysis of lead and copper ions in waste water samples.[4]
Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones).[5] It may be used in the hydrothermal synthesis of [Hg2(apca)2]n [apca = 3-aminopyrazine-2-carboxylate], a new mercury(I)-organic framework based on Hg22 + dumbbell.[6]

Pictogrammes

Skull and crossbonesHealth hazardEnvironment

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable


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Consulter la Bibliothèque de documents

Mercury (II) Acetate.
Dejmek M.
Synlett, 23(19), 2867-2868 (2012)
Polarography of olefin-mercury (II) acetate addition compounds.
Fleet B and Jee RD.
J. Electroanal. Chem. Interfac. Electrochem., 25(3), 397-408 (1973)
In situ hydrothermal synthesis of 2D mercury (I)-organic framework from 3-aminopyrazine-2-carboxylic acid and mercury (II) acetate.
Dehghanpour S, et al.
Inorganic Chemistry Communications, 25, 79-82 (2012)
Mercury-assisted solvolyses of alkyl halides: Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers.
McKillop A and Ford ME.
Tetrahedron, 30(15), 2467-2475 (1974)
Mercury (II) acetate-Nafion modified electrode for anodic stripping voltammetry of lead and copper with flow-injection analysis.
Dalangin RR and Gunasingham H.
Analytica Chimica Acta, 291(1), 81-87 (1994)

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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