62118

(R)-(+)-Limonène

analytical standard

• Synonyme(s) : (+)-p-Mentha-1,8-diène, (+)-Carvène, (R)-4-Isopropényl-1-méthyl-1-cyclohexène
• Formule empirique (notation de Hill) : C₁₀H₁₆
• Numéro CAS: 5989-27-5
• Poids moléculaire : 136.23
• Beilstein: 2204754
• Numéro CE : 227-813-5
• Numéro MDL: MFCD00062991
• Code UNSPSC : 85151701
• ID de substance PubChem : 329759707
• Nomenclature NACRES : NA.24

Propriétés

• Qualité: analytical standard
• Niveau de qualité: 100
• Densité de vapeur: 4.7 (vs air)
• Pression de vapeur: <3 mmHg ( 14.4 °C)
• Essai: ≥99.0% (sum of enantiomers, GC)
• Activité optique: [α]20/D +115.5±1°, c = 10% in ethanol
• Durée de conservation: limited shelf life, expiry date on the label
• Limite d'explosivité: 6.1 %
• Technique(s): HPLC: suitable; gas chromatography (GC): suitable
• Indice de réfraction: n20/D 1.473 (lit.); n20/D 1.473
• pb: 176-177 °C (lit.)
• Densité: 0.842 g/mL at 20 °C (lit.)
• Application(s): agriculture; cleaning products; cosmetics; environmental; flavors and fragrances; food and beverages; personal care
• Format: neat
• Température de stockage: 2-8°C
• Chaîne SMILES: CC(=C)[C@@H]1CCC(C)=CC1
• InChI: 1S/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,10H,1,5-7H2,2-3H3/t10-/m0/s1
• Clé InChI: XMGQYMWWDOXHJM-JTQLQIEISA-N

Description

Description générale

R)-(+)-Limonene is the R- and the predominant enantiomer of the cyclic monoterpene, limonene. It is present as the major constituent of essential oils extracted from oranges, grapefruits, and lemons. In addition, it is also added as a flavoring agent in different personal and household cleaning products, beverages, and confectionery goods. It is known to possess antioxidant, antimicrobial, antifungal, anti-inflammatory, and anti-carcinogenic properties.[1][1]
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Application

This analytical standard can also be used as follows:

• Analysis of alcoholic beverages for the determination of (R)-(+)-limonene by differential pulse voltammetry (DPV) using two novel electrochemical sensors
• Simultaneous determination of limonene and linalool in 10 perfume product samples by two-dimensional high-performance liquid chromatographic (HPLC) method combined with electrospray ionization tandem mass spectrometry (ESI-MS/MS)
• Determination of the enantiomeric composition of volatile chiral compounds, commonly present in three plant species from the Citrus genus by multidimensional gas chromatography (MDGC) coupled to mass spectrometry (MS)
• Multi-residue analysis of volatiles and fatty acids found in wild and cultivated fennel samples by a single extraction method and gas chromatographic-flame ionization detection (GC-FID)

Autres remarques

This compound is commonly found in plants of the genus: carum mentha salvia

Hydrogénation régiosélective des liaisons doubles exocycliques[2][3]; epoxydation régiosélective des liaisons doubles endocyclique[4]

Informations sur la sécurité

• Pictogrammes: GHS02,GHS08,GHS07,GHS09
• Mention d'avertissement: Danger
• Mentions de danger: H226,H304,H315,H317,H410
• Conseils de prudence: P210 - P273 - P280 - P301 + P310 - P303 + P361 + P353 - P331
• Classification des risques: Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 3 - Skin Irrit. 2 - Skin Sens. 1
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 2
• Point d'éclair (°F): 123.8 °F - closed cup
• Point d'éclair (°C): 51 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter