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45520

Supelco

Glufosinate-ammonium

PESTANAL®, analytical standard

Synonyme(s) :

DL-Phosphinothricine, Acide 2-amino-4-(hydroxyméthylphosphinyl)butyrique ammonium salt

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101.00 CHF

About This Item

Formule empirique (notation de Hill) :
C5H15N2O4P
Numéro CAS:
Poids moléculaire :
198.16
Beilstein:
8163399
Numéro CE :
Numéro MDL:
Code UNSPSC :
41116107
eCl@ss :
39110524
ID de substance PubChem :
Nomenclature NACRES :
NA.24

101.00 CHF


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Devis pour commande en gros

Qualité

analytical standard

Niveau de qualité

Gamme de produits

PESTANAL®

Durée de conservation

limited shelf life, expiry date on the label

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Pf

215 °C

Application(s)

agriculture
environmental

Format

neat

Chaîne SMILES 

N.CP(O)(=O)CCC(N)C(O)=O

InChI

1S/C5H12NO4P.H3N/c1-11(9,10)3-2-4(6)5(7)8;/h4H,2-3,6H2,1H3,(H,7,8)(H,9,10);1H3

Clé InChI

ZBMRKNMTMPPMMK-UHFFFAOYSA-N

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Description générale

Le glufosinate-ammonium est un analogue de l′acide glutamique.[1]

Application

Le glufosinate-ammonium peut être utilisé comme étalon de référence pour le dosage de l′analyte dans :
  • des échantillons de sérum humain, par extraction en phase solide (SPE) en mode mixte, dérivatisation de tert-butyldiméthylsilyl (t-BDMS) et chromatographie en phase gazeuse-spectrométrie de masse (GC-MS) avec mode de détection par impact d′électrons (Ei).des[1]
  • des échantillons d′eau, par nettoyage par échange d′ions et dérivatisation suivie d′une analyse par GC couplée à la spectrométrie de masse en tandem (MS/MS) avec mode de détection par fluorescence EI.[2]
  • des terres arables finlandaises, par chromatographie liquide haute performance avec détection par fluorescence (HPLC-FLD).[3]

Se référer au certificat d′analyse du produit pour en savoir plus sur les techniques instrumentales adaptées. Contacter le Service technique pour obtenir de l′aide.

Informations légales

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

Health hazardExclamation mark

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Repr. 1B - STOT RE 2

Code de la classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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Certificats d'analyse (COA)

Lot/Batch Number

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In this study, amphibian tadpoles of Hypsiboas pulchellus were exposed to herbicide Liberty®, which contains glufosinate ammonium (GLA), for 48 h to the following concentrations: 0 (control), 3.55, 4.74, 6.32, 8.43, 11.25, 15, 20, 26.6, and 35.5 mg GLA L(-1).
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Articles

Glyphosate and related compounds are measured in oatmeal and infant cereal using ion-exchange polymer-based particles for HPLC and SPE. Low level detection was obtained.

Glyphosate analysis: LC-MS/MS method with Supel™ Carbon LC U/HPLC column for stability and retention.

Protocoles

LC/MS Analysis of Glyphosate and Metabolites on apHera™ NH2, 2 mm I.D. Column

Questions

1–5 of 5 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  4. Product 45520, Glufosinate-ammonium, is a D, L isomer mix.  What proportions of each are in this product?

    1 answer
    1. This product is described as being racemic (DL).  Thus it would consist of 50% of the D- and 50% of the L- isomer.

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  5. How do I dissolve Product 45520, Glufosinate-ammonium?

    1 answer
    1. According to the chemicals encyclopedia published by the Royal Society of Chemistry, product 45520 is soluble in water.

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