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8.22287

Sigma-Aldrich

Hydrogen peroxide solution

30%, (stabilized) for synthesis

Synonyme(s) :

Hydrogen peroxide solution, Perhydrol

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1 L
30.10 CHF
2.5 L
59.30 CHF

30.10 CHF

Date d'expédition estimée le21 mai 2025

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1 L
30.10 CHF
2.5 L
59.30 CHF

About This Item

Formule empirique (notation de Hill) :
H2O2
Numéro CAS:
7722-84-1
Poids moléculaire :
34.01
Beilstein:
3587191
Numéro MDL:
MFCD00011333
Code UNSPSC :
12352304
Nomenclature NACRES :
NA.22

30.10 CHF

Date d'expédition estimée le21 mai 2025

Devis pour commande en gros

Nom du produit

Peroxyde d'hydrogène solution, (stabilized) for synthesis

Qualité

for synthesis

Niveau de qualité

200

Pression de vapeur

18 hPa ( 20 °C)
23.3 mmHg ( 30 °C)

Forme

liquid

Pertinence de la réaction

reagent type: oxidant

pH

2-4 (20 °C in H2O)

pb

107 °C/1013 hPa

Pf

-26 °C

Densité

1.11 g/cm3 at 20 °C

Température de stockage

2-25°C

Chaîne SMILES 

OO

InChI

1S/H2O2/c1-2/h1-2H

Clé InChI

MHAJPDPJQMAIIY-UHFFFAOYSA-N

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Application

Hydrogen peroxide 30% can be used as an oxidizing agent:
  • To synthesize 5-bromo-2-nitropyridine from 5-bromo-2-aminopyridine in the presence of H2SO4.[1]
  • For the oxidation of aromatic and aliphatic sulfides to sulfoxides or sulfones.[2]
  • For the epoxidation of terminal olefins using a mixture of Na2WO4 dihydrate, (aminomethyl)phosphonic acid, and methyltrin-octylammonium hydrogensulfate.[3]
  • To prepare adipic acid via oxidation of cyclohexanone and cyclohexanol in the presence of H2WO4 as a catalyst.[4]
  • To convert cyclopentanone to δ-valerolactone via Baeyer−Villiger-oxidation in the presence of a solid acid catalyst.[5]

Remarque sur l'analyse

Assay (manganometric): 29.0 - 31.0 %
Density (d 20/4): 1.11 - 1.12 g/cm³

Pictogrammes

Corrosion
GHS05

Mention d'avertissement

Danger

Mentions de danger

H318

Conseils de prudence

P280 - P305 + P351 + P338

Classification des risques

Eye Dam. 1

Code de la classe de stockage

5.1B - Oxidizing hazardous materials

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

not combustible

Point d'éclair (°C)

not combustible

Certificats d'analyse (COA)

Recherchez un Certificats d'analyse (COA) en saisissant le numéro de lot du produit. Les numéros de lot figurent sur l'étiquette du produit après les mots "Lot" ou "Batch".

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Consulter la Bibliothèque de documents

A green method of adipic acid synthesis: organic solvent-and halide-free oxidation of cycloalkanones with 30% hydrogen peroxide
Usui Y and Sato K
Green Chemistry, 5(4), 373-375 (2003)
Baeyer-Villiger-oxidation of cyclopentanone with aqueous hydrogen peroxide by acid heterogeneous catalysis
Fischer J and Holderich WF
Applied Catalysis A: General, 180(1-2), 435-443 (1999)
Oxidation of sulfides to sulfoxides and sulfones with 30% hydrogen peroxide under organic solvent-and halogen-free conditions
Sato K, et al.
Tetrahedron, 57(13), 2469-2476 (2001)
Handling hydrogen peroxide oxidations on a Large Scale: synthesis of 5-bromo-2-nitropyridine
Agosti A, et al.
Organic Process Research & Development, 21(3), 451-459 (2017)
A Practical Method for Epoxidation of Terminal Olefins with 30 Hydrogen Peroxide under Halide-Free Conditions.
Kazuhiko Sato et al.
The Journal of organic chemistry, 61(23), 8310-8311 (1996-11-15)

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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