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754935

Sigma-Aldrich

Ethyl methyl carbonate

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99%

Synonyme(s) :

Carbonic acid ethyl methyl ester, EMC, Methyl ethyl carbonate

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207.00 CHF

About This Item

Formule empirique (notation de Hill) :
C4H8O3
Numéro CAS:
Poids moléculaire :
104.10
Numéro MDL:
Code UNSPSC :
26111700
ID de substance PubChem :
Nomenclature NACRES :
NA.23

207.00 CHF


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Essai

99%

Forme

liquid

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Indice de réfraction

n20/D 1.378

pb

101 °C

Pf

-55 °C

Densité

1.006 g/mL at 25 °C

Application(s)

battery manufacturing

Autre catégorie plus écologique

Chaîne SMILES 

CCOC(=O)OC

InChI

1S/C4H8O3/c1-3-7-4(5)6-2/h3H2,1-2H3

Clé InChI

JBTWLSYIZRCDFO-UHFFFAOYSA-N

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Description générale

Ethyl methyl carbonate (EMC) is a low viscosity solvent, generally prepared by the esterification of chloroformate with ethanol. It can also be prepared by transesterification of dimethyl carbonate (DMC) with ethanol.[1][2]
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Application

EMC is majorly utilized as a co-solvent in the nonaqueous electrolyte. It enhances the energy density and discharge capacity of lithium-ion batteries.[1][2][3][4]

Pictogrammes

Flame

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Flam. Liq. 2

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

75.0 °F

Point d'éclair (°C)

23.9 °C


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Certificats d'analyse (COA)

Lot/Batch Number

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Zeolitic imidazolate framework as efficient heterogeneous catalyst for the synthesis of ethyl methyl carbonate
Zhou X, et al.
J. Mol. Catal. A: Chem., 366, 43-47 (2013)
Lithium difluoro (oxalato) borate/ethylene carbonate+ propylene carbonate+ ethyl (methyl) carbonate electrolyte for LiMn2O4 cathode
Fu MH, et al.
Journal of Power Sources, 195(3), 862-866 (2010)
Metal-organic frameworks as an acid catalyst for the synthesis of ethyl methyl carbonate via transesterification
Zhou Y, et al.
J. Mol. Catal. A: Chem., 308(1-2), 68-72 (2009)
Liu J, et al.
Electrochemical Communications, 13(3), 269-269 (2011)
McEwen A, et al.
Journal of the Electrochemical Society, 146(5), 1687-1687 (1999)

Articles

Experts discuss challenges and production processes of nickel-rich layered oxide cathode materials in energy storage systems.

Solid oxide fuel cells and electrolyzers show potential for chemical-to-electrical energy conversion, despite early development stages.

Li-ion batteries are currently the focus of numerous research efforts with applications designed to reduce carbon-based emissions and improve energy storage capabilities.

Lithium-ion batteries offer high energy density and cyclic performance for portable electronic devices.

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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Hello, does anyone have the enthalpy of combustion of ethyl methyl carbonate? Is for preventing the fire risk at its storage.

    1 answer
    1. The enthalpy of combustion of ethyl methyl carbonate is not determined for this product. This product should be stored in room temperature and kept tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. It is stable under recommended storage conditions.

      For more safety information, please view the product Safety Data Sheet: https://www.sigmaaldrich.com/sds/aldrich/754935

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