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Sigma-Aldrich

Titanium(IV) isopropoxide

packaged for use in deposition systems

Synonyme(s) :

TTIP, Tetraisopropyl orthotitanate

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About This Item

Formule linéaire :
Ti[OCH(CH3)2]4
Numéro CAS:
Poids moléculaire :
284.22
Numéro Beilstein :
3679474
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352107
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Pureté

99.999%

Forme

liquid

Pertinence de la réaction

core: titanium
reagent type: catalyst

Indice de réfraction

n20/D 1.464 (lit.)

Point d'ébullition

232 °C (lit.)

Pf

14-17 °C (lit.)

Densité

0.96 g/mL at 20 °C (lit.)

Chaîne SMILES 

CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C

InChI

1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4

Clé InChI

VXUYXOFXAQZZMF-UHFFFAOYSA-N

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Description générale

Atomic number of base material: 22 Titanium

Application

Novel metal oxide/phosphonate hybrids were formed from titanium(IV) isopropoxide in a two-step sol-gel process. Starting material for barium-strontium-titanate thin films. Used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes. Applied in the formation of a heterosupermolecule consisting of a TiO2 nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated.

Pictogrammes

FlameExclamation mark

Mention d'avertissement

Warning

Mentions de danger

Classification des risques

Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

Organes cibles

Central nervous system

Code de la classe de stockage

3 - Flammable liquids

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

105.8 °F - Pensky-Martens closed cup

Point d'éclair (°C)

41 °C - Pensky-Martens closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Certificats d'analyse (COA)

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Consulter la Bibliothèque de documents

Manas K Panda et al.
Dalton transactions (Cambridge, England : 2003), 39(9), 2428-2440 (2010-02-18)
Controlled oxidation of organic sulfides to sulfoxides under ambient conditions has been achieved by a series of titanium isopropoxide complexes that use environmentally benign H(2)O(2) as a primary oxidant. Specifically, the [N,N'-bis(2-oxo-3-R(1)-5-R(2)-phenylmethyl)-N,N'-bis(methylene-R(3))-ethylenediamine]Ti(O(i)Pr)(2) [R(1) = t-Bu, R(2) = Me, R(3) =
Tadashi Kokubo et al.
Journal of materials science. Materials in medicine, 19(2), 695-702 (2007-07-11)
A rectangular specimen of polyethylene terephthalate (PET) was soaked in a titania solution composed of titanium isopropoxide, water, ethanol and nitric acid at 25 degrees C for 1 h. An amorphous titanium oxide was formed uniformly on the surface of
Henrique Antonio Mendonça Faria et al.
Materials science & engineering. C, Materials for biological applications, 56, 260-268 (2015-08-08)
The structural and electronic properties of titanium oxide nanotubes (TiO2) have attracted considerable attention for the development of therapeutic devices and imaging probes for nanomedicine. However, the fluorescence response of TiO2 has typically been within ultraviolet spectrum. In this study
Yann Sarazin et al.
Dalton transactions (Cambridge, England : 2003), (2)(2), 340-350 (2005-12-21)
The reactions of the bulky amino-bis(phenol) ligand Me(2)NCH(2)CH(2)N[CH(2)-3,5-Bu(t)(2)-C(6)H(2)OH-2](2)(1-H(2)) with Zn[N(SiMe(3))(2)](2)(4), [Mg[N(SiMe(3))(2)](2)](2)(5) and Ca[N(SiMe(3))(2)](2)(THF)(2)(6) yield the complexes 1-Zn, 1-Mg and 1-Ca in good yields. The X-ray structure of 1-Ca showed the complex to be dimeric, with calcium in a distorted octahedral
Alfred J Wooten et al.
Organic letters, 9(3), 381-384 (2007-01-26)
[reaction: see text] We report the catalytic asymmetric allylation of ketones under highly concentrated reaction conditions with a catalyst generated from titanium tetraisopropoxide and BINOL (1:2 ratio) in the presence of isopropanol. This catalyst promotes the addition of tetraallylstannane to

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