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517933

Sigma-Aldrich

Iron(II) acetate

≥99.99% trace metals basis

Synonyme(s) :

Ferrous acetate, Iron acetate [Fe(OAc)2 ], Iron diacetate

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About This Item

Formule linéaire :
Fe(CO2CH3)2
Numéro CAS:
Poids moléculaire :
173.93
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352103
ID de substance PubChem :
Nomenclature NACRES :
NA.23
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Niveau de qualité

Essai

≥99.99% trace metals basis

Forme

solid

Pertinence de la réaction

core: iron

Pf

190-200 °C (dec.) (lit.)

Chaîne SMILES 

CC(=O)O[Fe]OC(C)=O

InChI

1S/2C2H4O2.Fe/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

Clé InChI

LNOZJRCUHSPCDZ-UHFFFAOYSA-L

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Description générale

Iron(II) acetate, also known as ferrous acetate. It finds applications in the dye industry, organic synthesis, and as a precursor for other iron compounds. Additionally, it is also used as a catalyst in organic oxidation reactions.

Application

Iron(II) acetate can be used as:
  • A precursor for synthesizing iron oxide and iron-based nanostructures which are employed as anode materials for lithium-ion batteries and supercapacitors.
  • A precursor in the synthesis of iron oxide nanoparticles. These particles are incorporated into carbon nanofibers for use in supercapacitor applications.
  • A precursor to synthesize hematite nanoparticles for applications in solar cells. These nanoparticles exhibit shape-dependent optical properties and can be used for imaging, photocatalysis, and solar cells. The product was used to synthesize iron oxide nanoparticles which was further used to form iron oxide-poly(ethylene glycol) core-shell nanoparticles (NPs). The core-shell NPs were studied for self-assembly at liquid–liquid interfaces (SALI) forming monolayers.

Conditionnement

The product was used to synthesize iron oxide nanoparticles which was further used to form iron oxide-poly(ethylene glycol) core-shell nanoparticles (NPs). The core-shell NPs were studied for self-assembly at liquid–liquid interfaces (SALI) forming monolayers.[1][2]

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves


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Certificats d'analyse (COA)

Lot/Batch Number

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Consulter la Bibliothèque de documents

Preparation of Iron (II) acetate from magnetite by selective precipitation
Oh HS, et al. et al.
BIWIC 2007: 14th International Workshop on Industrial Crystallization, 214-214 null
Self-Assembly of Iron Oxide-Poly (ethylene glycol) Core?Shell Nanoparticles at Liquid?Liquid Interfaces.
Isa L, et al.
Chimia, 64(3), 145-149 (2010)

Articles

Prof. Randal Lee discusses iron oxide magnetic nanospheres and nanocubes design considerations for biosensing applications.

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. Hi!, Iron(II) acetate 99.99% (Cas 3094-87-9, 517933) is completely Fe(II)? i need information of Fe(III) impurity in it

    1 answer
    1. This product is not tested for the presence of Iron(III) acetate. However, the minimum purity specification is 99.99%. The material is expected to be a white powder. Any substantive amount of Iron(III) acetate would impact the color.

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