481718

Iron(0) pentacarbonyl

>99.99% trace metals basis

• Synonyme(s) : Iron(0) carbonyl, Pentacarbonyliron(0)
• Formule linéaire : Fe(CO)₅
• Numéro CAS: 13463-40-6
• Poids moléculaire : 195.90
• Numéro CE : 236-670-8
• Numéro MDL: MFCD00011001
• Code UNSPSC : 12352103
• ID de substance PubChem : 24871777
• Nomenclature NACRES : NA.23

Propriétés

• Densité de vapeur: 6.74 (vs air)
• Niveau de qualité: 100
• Pression de vapeur: 35 mmHg ( 25 °C); 40 mmHg ( 30.3 °C)
• Essai: >99.99% trace metals basis
• Forme: liquid
• Température d'inflammation spontanée: 122 °F
• Pertinence de la réaction: core: iron; reagent type: catalyst
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Indice de réfraction: n20/D 1.5196 (lit.)
• pb: 103 °C (lit.)
• Pf: −20 °C (lit.)
• Densité: 1.49 g/mL at 25 °C (lit.)
• Autre catégorie plus écologique: , Aligned
• Température de stockage: 2-8°C
• Chaîne SMILES: [Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
• InChI: 1S/5CO.Fe/c5*1-2;
• Clé InChI: FYOFOKCECDGJBF-UHFFFAOYSA-N

Description

Description générale

Iron(0) pentacarbonyl is a straw-yellow to brilliant orange liquid soluble in organic solvents. It is widely used as a precursor for synthesizing iron oxide nanoparticles, which have applications in the field of energy conversion and storage due to their catalytic properties and ability to enhance electron transport.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Chemical Synthesis of Monodisperse Magnetic Nanoparticles

Iron(0) pentacarbonyl can be used:

• To fabricate Fe-based anode materials for high-performance aqueous secondary Ni−Fe batteries. It helps to achieve good safety, high power density, long term-life cycle, and high energy density.
• As a precursor to synthesize highly stable, colloidal magnetic iron nanoparticles with narrow size distribution. These nanoparticles are potential candidates for MRI contrasting agents and magnetically separable catalysts.
• To synthesize zero valent sustainable iron nanocatalysts for reduction reactions.

Reactant for:

• Addition reactions
• Decomposition via photolysis
• Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition
• Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides

• Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions

Informations sur la sécurité

• Pictogrammes: GHS02,GHS06
• Mention d'avertissement: Danger
• Mentions de danger: H225,H300 + H330,H311
• Conseils de prudence: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P304 + P340 + P310
• Classification des risques: Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 1
• Point d'éclair (°F): 5.0 °F - closed cup
• Point d'éclair (°C): -15 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter