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449504

Sigma-Aldrich

Bis(trifluorométhane)sulfonimide lithium salt

Synonyme(s) :

Bis(trifluorométhylsulfonyl)amine lithium salt, Bistrifluorométhanesulfonimidate de lithium

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126.00 CHF
50 G
318.00 CHF
250 G
1 160.00 CHF

126.00 CHF


Date d'expédition estimée le14 avril 2025


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10 G
126.00 CHF
50 G
318.00 CHF
250 G
1 160.00 CHF

About This Item

Formule linéaire :
CF3SO2NLiSO2CF3
Numéro CAS:
Poids moléculaire :
287.09
Beilstein:
6625414
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.22

126.00 CHF


Date d'expédition estimée le14 avril 2025


Devis pour commande en gros

Pf

234-238 °C (lit.)

Groupe fonctionnel

fluoro

Chaîne SMILES 

[Li]N(S(=O)(=O)C(F)(F)F)S(=O)(=O)C(F)(F)F

InChI

1S/C2F6NO4S2.Li/c3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/q-1;+1

Clé InChI

QSZMZKBZAYQGRS-UHFFFAOYSA-N

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Application

Bis(trifluoromethane)sulfonimide lithium salt (Li-TFSI) can be used:
  • As a chemical additive for improving the power conversion efficiencies in porphyrin-based organic solar cells.[1]     
  • As a reagent in the preparation of imidazolium core bearing monomer ionic liquids to develop polymerized ionic liquids.[2]
  • For the preparation of a chiral imidazolium salt via anion metathesis of the corresponding triflate.[3]       
  • In the synthesis of solid polymer electrolytes for lithium-ion batteries.[4][5] 
  • In the synthesis of polyelectrolyte reusable homogenous catalysts, which are used in the Diels–Alder reactions between isoprene and a variety of dienophiles.[6]
  • Used in the preparation of electrolytes for lithium batteries[7][8][9] and novel rare-earth Lewis acid catalysts.[10]

Autres remarques

For a review on fluorine containing nitrogen acids, see Coordination Chemistry Reviews.[11]

Pictogrammes

Skull and crossbonesHealth hazardCorrosion

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Oral

Organes cibles

Nervous system

Code de la classe de stockage

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Nanocomposites of titanium dioxide and polystyrene-poly (ethylene oxide) block copolymer as solid-state electrolytes for lithium metal batteries
Gurevitch I, et al.
Journal of the Electrochemical Society, 160(9), A1611-A1617 (2013)
An appraisal of tetraethylsulfamide as plasticizer for poly (ethylene oxide)- LiN (CF3SO2)2 rubbery electrolytes
Labreche C, et al.
Macromolecules, 29, 7795-7795 (1996)
Amino alcohol-derived chiral ionic liquids: structural investigations toward chiral recognition
Vasiloiu M, et al.
Tetrahedron Asymmetry, 26(18-19), 1069-1082 (2015)
Polyelectrolyte-catalyzed Diels-Alder reactions
Pothanagandhi N, et al.
Reactive and Functional Polymers, 106, 132-136 (2016)
13th ACS Winter Fluorine Conference, paper No. 8, January (1997)

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Due to the adverse impact of the continued use of fossil fuels on the earth’s environment and climate, researchers have been asked to develop new approaches for producing power using renewable sources like wind and solar energy

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Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. What is the purity?

    1 answer
    1. Product 449504 is not tested for purity. The product undergoes IR testing as well as carbon, hydrogen, and fluorine NMR to confirm its identity but minor impurities may be present.

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