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203548

Sigma-Aldrich

Lanthanum(III) nitrate hexahydrate

99.999% trace metals basis

Synonyme(s) :

Nitric acid, lanthanum (III) salt, hexahydrate

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25 G
125.00 CHF
100 G
292.00 CHF
500 G
1 080.00 CHF

125.00 CHF


Date d'expédition estimée le25 mars 2025


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25 G
125.00 CHF
100 G
292.00 CHF
500 G
1 080.00 CHF

About This Item

Formule linéaire :
La(NO3)3 · 6H2O
Numéro CAS:
Poids moléculaire :
433.01
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.23
Essai:
99.999% trace metals basis
Forme:
solid

125.00 CHF


Date d'expédition estimée le25 mars 2025


Devis pour commande en gros

Niveau de qualité

Essai

99.999% trace metals basis

Forme

solid

Pertinence de la réaction

reagent type: catalyst
core: lanthanum

Impuretés

≤15.0 ppm Trace Rare Earth Analysis

Pf

65-68 °C

Chaîne SMILES 

[La+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/La.3NO3.6H2O/c;3*2-1(3)4;;;;;;/h;;;;6*1H2/q+3;3*-1;;;;;;

Clé InChI

GJKFIJKSBFYMQK-UHFFFAOYSA-N

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Description générale

Lanthanum(III) nitrate hexahydrate is a transition metal catalyst widely used in many organic transformations such as chemoselective deprotection of acetonides, acetylation of alcohols, phenols, and amines with acetic anhydride, and synthesis of α-amino nitriles. It can also be used as a precursor in the preparation of lanthanum-based nanoparticles.

Application

Lanthanum(III) nitrate hexahydrate can be used as a catalyst in the synthesis of:
  • α-aminonitriles by a one-pot three-component coupling of the carbonyl compound, amine, and TMSCN.
  • Acetals and geminal diacetates (acylals)from aldehydes.
  • Bis(indolyl) methanes under solvent‐free conditions.
It can also be used as a starting material for the electrochemical synthesis of LaMnO3 thin films and solvothermal synthesis of doped lanthanide oxysulfide (La2O2S).

Caractéristiques et avantages

  • Thermal stability
  • Low toxicity
  • Mild reaction condition
  • Chemoselectivity
  • Low cost

Pictogrammes

Flame over circleCorrosionEnvironment

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 2

Code de la classe de stockage

5.1B - Oxidizing hazardous materials

Classe de danger pour l'eau (WGK)

WGK 2

Équipement de protection individuelle

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificats d'analyse (COA)

Lot/Batch Number

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Consulter la Bibliothèque de documents

J Tyler Mefford et al.
Physical chemistry chemical physics : PCCP, 21(6), 3327-3338 (2019-01-29)
Perovskite oxides are active room-temperature bifunctional oxygen electrocatalysts in alkaline media, capable of performing the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) with lower combined overpotentials relative to their precious metal counterparts. However, their semiconducting nature necessitates the
Wen-Feng Zhao et al.
Dalton transactions (Cambridge, England : 2003), 41(33), 10091-10096 (2012-08-02)
The reaction between polyoxometalate (POM) [TBA](12)[WZn{Zn(H(2)O)}(2)(ZnW(9)O(34))(2)] (TBA = tetrabutyl ammonium) and lanthanide (Ln) nitrate (Ln = La, Eu and Tb) in a mixed solvent of CH(3)CN and DMF yielded three noncentrosymmetric diamondoid Ln-POM solid materials, {[Ln(2)(DMF)(8)(H(2)O)(6)][ZnW(12)O(40)]}·4DMF (Ln-POM; Ln = La
L P Lopatina et al.
Biofizika, 50(6), 1120-1124 (2005-12-20)
The influence of lanthanoids on exocytosis was investigated. It was shown that gadolinium increases the spontaneous release of the glutamate nonmetabolizing analogue [3H]D-aspartate. It was established using the fluorescent dye acridine orange that gadolinium and lanthanum induce exocytosis. The effect
Emanuela Mazzon et al.
Shock (Augusta, Ga.), 25(5), 515-521 (2006-05-09)
Small intestine permeability is frequently altered in inflammatory bowel diseases and may be caused by the translocation of intestinal toxins through leaky small intestine tight junctions (TJs) and adherence. Thus, the aim of the present study was to examine the
Liping Wei et al.
Microvascular research, 80(1), 158-165 (2010-01-19)
The PKC-beta inhibitor ruboxistaurin (RBX or LY333531) prevents diabetic renal and retinal microvascular complications. However, the effect of RBX on diabetic cardiac microvascular dysfunction is still unclear. In this study, we aimed to investigate the effects and mechanisms of RBX

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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