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Epoxidation of alkenes through oxygen activation over a bifunctional CuO/Al2O3 catalyst.

Chemical communications (Cambridge, England) (2013-01-30)
Nicola Scotti, Nicoletta Ravasio, Federica Zaccheria, Rinaldo Psaro, Claudio Evangelisti
ZUSAMMENFASSUNG

The epoxidation of alkenes was carried out over a CuO/Al(2)O(3) catalyst using cumene as an oxygen carrier, through a one-pot reaction, giving high conversion and selectivity with different substrates. Trans-β-methylstyrene gave the corresponding epoxide in 95% yield after 3 h.

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Kupfer(II)-oxid, nanopowder, <50 nm particle size (TEM)
Sigma-Aldrich
Kupfer(II)-oxid, ACS reagent, ≥99.0%
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Kupfer(II)-oxid, powder, <10 μm, 98%
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Kupfer(II)-oxid, powder, 99.99% trace metals basis
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Kupfer(II)-oxid, needles, mixture of CuO and Cu2O, ACS reagent
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Kupfer(II)-oxid auf Aluminiumoxid, 14-30 mesh, extent of labeling: 13 wt. % loading
Sigma-Aldrich
Kupfer(II)-oxid, 99.999% trace metals basis
Sigma-Aldrich
Kupfer(II)-oxid, powder, 99.995% trace metals basis