B56501

4-Bromoanisole

≥99.0%

• Synonyme(s) : 1-Bromo-4-methoxybenzene
• Formule linéaire : BrC₆H₄OCH₃
• Numéro CAS: 104-92-7
• Poids moléculaire : 187.03
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 24891850
• EC Number: 203-252-1
• Beilstein/REAXYS Number: 1237590
• MDL number: MFCD00000097
• eCl@ss: 32150313
• Assay: ≥99.0%
• Form: liquid

Propriétés

• Quality Segment: 100
• assay: ≥99.0%
• form: liquid
• refractive index: n20/D 1.564 (lit.)
• bp: 223 °C (lit.)
• mp: 9-10 °C (lit.)
• density: 1.494 g/mL at 25 °C (lit.)
• functional group: bromo
• SMILES string: COc1ccc(Br)cc1
• InChI: 1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3
• InChI key: QJPJQTDYNZXKQF-UHFFFAOYSA-N

Description

General description

4-Bromoanisole is a useful brominating reagent. It is formed as reaction product in the reaction between HOBr and anisole. Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied. Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.

Application

4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.

Informations sur la sécurité

• Pictogrammes: GHS07
• Mot-clé: Warning
• Codes de danger: H302,H315
• Mentions de précaution: P264 - P270 - P280 - P301 + P312 - P302 + P352 - P332 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Skin Irrit. 2
• Classe de stockage: 10 - Combustible liquids
• WGK: WGK 2
• Point d'éclair (°F): 201.2 °F
• Point d'éclair (°C): 94 °C
• EPI (équipement de protection individuelle): Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)