CRM69034

Cycloate

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Synonym(s): S-Ethyl N-cyclohexyl-N-ethylthiocarbamate
• Empirical Formula (Hill Notation): C₁₁H₂₁NOS
• CAS Number: 1134-23-2
• Molecular Weight: 215.36
• Beilstein: 2937178
• MDL number: MFCD00055341
• UNSPSC Code: 41116107
• NACRES: NA.24

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• format: neat
• SMILES string: CCSC(=O)N(CC)C1CCCCC1
• InChI: 1S/C11H21NOS/c1-3-12(11(13)14-4-2)10-8-6-5-7-9-10/h10H,3-9H2,1-2H3
• InChI key: DFCAFRGABIXSDS-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Cycloate-a thiocarbamate herbicide and a lipid biosynthesis inhibitor, finds its use in the control of annual grass weeds, perennial grasses, and annual broad-leaved weeds in spinach, sugar beet, fodder beet, and
beetroot.
Cycloate is not approved for its use in the European Union (EU) as a plant protection agent. This is in accordance with Regulation (EC) No 1107/2009 of the European Parliament and repealing the Council Directives 79/117/EEC and 91/414/EEC. But a default maximum residue limit (MRL) of 0.01 mg/kg has been set as per Art 18(1)(b) Reg 396/2005.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The cycloate CRM may also find given below uses:

• Solid phase extraction (SPE) followed by gas chromatography-mass spectrometry (GC-MS) analysis of 88 pesticide residues in strawberry, raspberry, blueberry, and grape samples
• Multi-residue determination of 118 pesticide residues in tea samples by solid phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS)
• Multi-class analysis of 21 pesticides in Chios mastic gum by QuEChERS for sample treatment, UHPLC for separation, and electrospray triple quadrupole mass spectrometry (ESI-MS/MS) for quantification
• Development and validation of a multi-residue method for the detection and quantification of 109 pesticides in tomato samples by modified QuEChERS based sample clean-up, followed by liquid chromatography-tandem mass spectrometry (LC-MS/MS)
• Evaluation of a method for multi-class analysis of 170 pesticide residues in soya nutraceutical capsule samples by QuEChERS based extraction and GC-MS/MS quantitation
• Detection and measurement of 115 pesticide residues in 400 commercial orange samples by high-performance liquid chromatography-triple-quadrupole mass spectrometry (LC-MS/MS) coupled with modified QuEChERS based sample treatment

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS06,GHS09
• Signal Word: Danger
• Hazard Statements: H331,H411
• Precautionary Statements: P261 - P271 - P273 - P304 + P340 + P311 - P391 - P403 + P233
• Hazard Classifications: Acute Tox. 3 Inhalation - Aquatic Chronic 2
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 2
• Flash Point(F): 271.4 °F
• Flash Point(C): 133 °C