20989

Cesium fluoride

BioUltra, ≥99.0% (F)

• Synonyme(s) : NSC 84270
• Formule empirique (notation de Hill) : CsF
• Numéro CAS: 13400-13-0
• Poids moléculaire : 151.90
• NACRES: NA.25
• PubChem Substance ID: 57647888
• UNSPSC Code: 12352302
• EC Number: 236-487-3
• MDL number: MFCD00010960
• Assay: ≥99.0% (F)
• Grade: reagent grade
• Solubility: H₂O: 3 M at 20 °C, clear, colorless

Propriétés

• grade: reagent grade
• Quality Segment: 100
• product line: BioUltra
• assay: ≥99.0% (F)
• impurities: insoluble matter, passes filter test, ≤0.005% total nitrogen (N)
• loss: ≤0.5% loss on drying, 110 °C
• pH: 6.5-7.5 (25 °C, 3 M in H₂O)
• mp: 682 °C (lit.)
• solubility: H₂O: 3 M at 20 °C, clear, colorless
• density: 4.115 g/mL at 25 °C (lit.)
• anion traces: chloride (Cl^-): ≤500 mg/kg, sulfate (SO₄^2-): ≤50 mg/kg
• cation traces: Al: ≤10 mg/kg, As: ≤0.5 mg/kg, Ba: ≤10 mg/kg, Bi: ≤5 mg/kg, Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤30 mg/kg, K: ≤100 mg/kg, Li: ≤5 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Mo: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Sr: ≤5 mg/kg, Zn: ≤5 mg/kg
• λ: 3 M in H₂O
• UV absorption: λ: 260 nm A_max: 0.05, λ: 280 nm A_max: 0.05
• SMILES string: [F-].[Cs+]
• InChI: 1S/Cs.FH/h;1H/q+1;/p-1
• InChI key: XJHCXCQVJFPJIK-UHFFFAOYSA-M

Description

Application

Reactant for:

• Preparation of building blocks for synthesis of fluoroallylic compounds
• Synthesis of alcohols via hydrolysis of alkyl silyl ethers at neutral pH in buffered mixed organic-aqueous solutions
• Nucleophilic fluorination of alkynyliodonium salts to form fluorovinylic compounds
• Nucleophilic aromatic substitution (SNAr) reactions

Used in the successful synthesis of a single-crystal Dion-Jacobson phase, CsLaTa₂O₇, that has applications in photocatalysis and superconductivity.

Informations sur la sécurité

• pictograms: GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H302,H318,H361d,H373,H412
• pcodes: P202 - P273 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - STOT RE 2
• target_organs: Kidney,Adrenal gland
• supp_hazards: EUH032
• Classe de stockage: 11 - Combustible Solids
• wgk: WGK 2
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges